Optical and microwave properties of metal-ammonia solutions

Morrel H. Cohen, Itzhak Webman, Joshua Jortner

Research output: Contribution to journalArticle

10 Scopus citations

Abstract

In this paper we present an analysis of the optical and microwave properties of metal-ammonia solutions in the concentration range 2-9 MPM. The analysis rests on the physical picture of a continuous metal-nonmetal transition, intermediated by microscopic inhomogeneities originating from bimodal concentration fluctuations. Effective-medium theory for the complex dielectric constant gives a good account of the optical properties of Li-NH 3 in the energy range 0.6-1.4 eV. On the other hand, effective-medium theory is inadequate for the microwave properties, and results of numerical simulation are presented.

Original languageEnglish (US)
Pages (from-to)2013-2019
Number of pages7
JournalThe Journal of chemical physics
Volume64
Issue number5
DOIs
StatePublished - Jan 1 1976
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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