Observation of Cu2+-H2 interactions in a fully desolvated socialite-type metal-organic framework

Mircea Dincǎ; Won Seok Han; Yun Liu; Anne Dailly; Craig M. Brown; Jeffrey R. Long

doi:10.1002/anie.200604362

Observation of Cu²⁺-H₂ interactions in a fully desolvated socialite-type metal-organic framework

Mircea Dincǎ
, Won Seok Han
, Yun Liu
, Anne Dailly
, Craig M. Brown
, Jeffrey R. Long

Research output: Contribution to journal › Article › peer-review

392 Scopus citations

Abstract

(Figure Presented) Metal-H₂ binding: A new tetrazolate-based metal-organic framework exhibits high H₂ uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu²⁺ ions within the framework provides strong binding sites for H₂ molecules (see picture; Cu purple, C gray, N blue, Cl green).

Original language	English (US)
Pages (from-to)	1419-1422
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	9
DOIs	https://doi.org/10.1002/anie.200604362
State	Published - 2007
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

Copper
Hydrogen metal-organic frameworks
Microporous materials
Neutron diffraction

Access to Document

10.1002/anie.200604362

Cite this

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title = "Observation of Cu2+-H2 interactions in a fully desolvated socialite-type metal-organic framework",

abstract = "(Figure Presented) Metal-H2 binding: A new tetrazolate-based metal-organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N blue, Cl green).",

keywords = "Copper, Hydrogen metal-organic frameworks, Microporous materials, Neutron diffraction",

author = "Mircea Dincǎ and Han, \{Won Seok\} and Yun Liu and Anne Dailly and Brown, \{Craig M.\} and Long, \{Jeffrey R.\}",

year = "2007",

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T1 - Observation of Cu2+-H2 interactions in a fully desolvated socialite-type metal-organic framework

AU - Dincǎ, Mircea

AU - Han, Won Seok

AU - Liu, Yun

AU - Dailly, Anne

AU - Brown, Craig M.

AU - Long, Jeffrey R.

PY - 2007

Y1 - 2007

N2 - (Figure Presented) Metal-H2 binding: A new tetrazolate-based metal-organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N blue, Cl green).

AB - (Figure Presented) Metal-H2 binding: A new tetrazolate-based metal-organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N blue, Cl green).

KW - Copper

KW - Hydrogen metal-organic frameworks

KW - Microporous materials

KW - Neutron diffraction

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