o-carboranylcarbene. A largely localized divalent carbon intermediate

Richard S. Mutton; Heinz D. Roth; Sarangan Chari

doi:10.1021/j150607a004

o-carboranylcarbene. A largely localized divalent carbon intermediate

Richard S. Mutton, Heinz D. Roth, Sarangan Chari

Chemistry

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4 Scopus citations

Abstract

Triplet EPR spectra of o-carboranylcarbene and its 2-methyl derivative have been observed at 5 K in frozen solutions. The zero-field splitting parameters indicate little delocalization of the π spin density onto the carboranyl moiety, in contrast to the results observed for benzenoid aromatic moieties.

Original language	English (US)
Pages (from-to)	753-754
Number of pages	2
Journal	Journal of physical chemistry
Volume	85
Issue number	7
DOIs	https://doi.org/10.1021/j150607a004
State	Published - 1981

All Science Journal Classification (ASJC) codes

General Engineering
Physical and Theoretical Chemistry

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10.1021/j150607a004

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@article{1318582f570140e1a67c4c995115f1a5,

title = "o-carboranylcarbene. A largely localized divalent carbon intermediate",

abstract = "Triplet EPR spectra of o-carboranylcarbene and its 2-methyl derivative have been observed at 5 K in frozen solutions. The zero-field splitting parameters indicate little delocalization of the π spin density onto the carboranyl moiety, in contrast to the results observed for benzenoid aromatic moieties.",

author = "Mutton, {Richard S.} and Roth, {Heinz D.} and Sarangan Chari",

year = "1981",

doi = "10.1021/j150607a004",

language = "English (US)",

volume = "85",

pages = "753--754",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "7",

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TY - JOUR

T1 - o-carboranylcarbene. A largely localized divalent carbon intermediate

AU - Mutton, Richard S.

AU - Roth, Heinz D.

AU - Chari, Sarangan

PY - 1981

Y1 - 1981

N2 - Triplet EPR spectra of o-carboranylcarbene and its 2-methyl derivative have been observed at 5 K in frozen solutions. The zero-field splitting parameters indicate little delocalization of the π spin density onto the carboranyl moiety, in contrast to the results observed for benzenoid aromatic moieties.

AB - Triplet EPR spectra of o-carboranylcarbene and its 2-methyl derivative have been observed at 5 K in frozen solutions. The zero-field splitting parameters indicate little delocalization of the π spin density onto the carboranyl moiety, in contrast to the results observed for benzenoid aromatic moieties.

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UR - http://www.scopus.com/inward/citedby.url?scp=0345421606&partnerID=8YFLogxK

U2 - 10.1021/j150607a004

DO - 10.1021/j150607a004

M3 - Article

AN - SCOPUS:0345421606

SN - 0022-3654

VL - 85

SP - 753

EP - 754

JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 7

ER -

o-carboranylcarbene. A largely localized divalent carbon intermediate

Abstract

All Science Journal Classification (ASJC) codes

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