TY - JOUR
T1 - Non-random distribution of adsorbates on catalytic surfaces
T2 - The role of interactions between adsorbates
AU - Kaza, Kesava Rao
AU - Sundaresan, Sankaran
N1 - Funding Information:
Acknowledgment is made to the donors of the Petroleum Research Fund, administered by the ACS (PRF # 13482-AC5), The Camille and Henry Dreyfus Foundation, Inc. (SG-31-81), the Atlantic Richfield Foundation, and the Shell Foundation for support of this work.
PY - 1985/1
Y1 - 1985/1
N2 - It has been repeatedly stressed in the literature that the commonly invoked assumption of a random distribution of adsorbates on the catalyst surface is suspect under certain operating conditions. Nonrandom distribution of the adsorbates can occur as a result of interaction between adsorbates and/or their inadequate mobility. We have studied the effect of adsorbate interactions on the rates and stability of catalytic reactions, and the salient features are outlined with several examples. An analysis of the thermodynamic data concerning the oxidation of SO2on platinum is presented within the framework of the proposed model.
AB - It has been repeatedly stressed in the literature that the commonly invoked assumption of a random distribution of adsorbates on the catalyst surface is suspect under certain operating conditions. Nonrandom distribution of the adsorbates can occur as a result of interaction between adsorbates and/or their inadequate mobility. We have studied the effect of adsorbate interactions on the rates and stability of catalytic reactions, and the salient features are outlined with several examples. An analysis of the thermodynamic data concerning the oxidation of SO2on platinum is presented within the framework of the proposed model.
KW - Adsorbate interactions
KW - Phase separation of adsorbates
KW - Sulfur dioxide oxidation on noble metals
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U2 - 10.1080/00986448508911655
DO - 10.1080/00986448508911655
M3 - Article
AN - SCOPUS:33751340201
SN - 0098-6445
VL - 32
SP - 333
EP - 355
JO - Chemical Engineering Communications
JF - Chemical Engineering Communications
IS - 6
ER -