N,N-diethyldithiocarbamato-κ2S,S′bis-(1, 10-phenanthroline)sodium(I)

Tihana Mirkovic; Sreekumari P. Nair; Gregory D. Scholes; Alan J. Lough

doi:10.1107/S1600536806009445

N,N-diethyldithiocarbamato-κ²S,S′bis-(1, 10-phenanthroline)sodium(I)

Tihana Mirkovic, Sreekumari P. Nair, Gregory D. Scholes, Alan J. Lough

Research output: Contribution to journal › Article

6 Scopus citations

Abstract

In the title molecule, [Na(C₅H₁₀NS ₂)(C₁₂H₈N₂)₂], which has crystallographic twofold symmetry, the coordination geometry of the Na atom is intermediate between octahedral and trigonal prismatic, coordinated by two S atoms of an N,N-diethyldithiocarbamate ligand and four chelating N atoms of two 1,10-phenanthroline ligands. In the crystal structure, weak C-H⋯S and π-π stacking interactions form chains of rings.

Original language	English (US)
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	4
DOIs	https://doi.org/10.1107/S1600536806009445
State	Published - Apr 1 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536806009445

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Mirkovic, T., Nair, S. P., Scholes, G. D., & Lough, A. J. (2006). N,N-diethyldithiocarbamato-κ²S,S′bis-(1, 10-phenanthroline)sodium(I). Acta Crystallographica Section E: Structure Reports Online, 62(4). https://doi.org/10.1107/S1600536806009445

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title = "N,N-diethyldithiocarbamato-κ2S,S′bis-(1, 10-phenanthroline)sodium(I)",

abstract = "In the title molecule, [Na(C5H10NS 2)(C12H8N2)2], which has crystallographic twofold symmetry, the coordination geometry of the Na atom is intermediate between octahedral and trigonal prismatic, coordinated by two S atoms of an N,N-diethyldithiocarbamate ligand and four chelating N atoms of two 1,10-phenanthroline ligands. In the crystal structure, weak C-H⋯S and π-π stacking interactions form chains of rings.",

author = "Tihana Mirkovic and Nair, {Sreekumari P.} and Scholes, {Gregory D.} and Lough, {Alan J.}",

year = "2006",

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language = "English (US)",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - N,N-diethyldithiocarbamato-κ2S,S′bis-(1, 10-phenanthroline)sodium(I)

AU - Mirkovic, Tihana

AU - Nair, Sreekumari P.

AU - Scholes, Gregory D.

AU - Lough, Alan J.

PY - 2006/4/1

Y1 - 2006/4/1

N2 - In the title molecule, [Na(C5H10NS 2)(C12H8N2)2], which has crystallographic twofold symmetry, the coordination geometry of the Na atom is intermediate between octahedral and trigonal prismatic, coordinated by two S atoms of an N,N-diethyldithiocarbamate ligand and four chelating N atoms of two 1,10-phenanthroline ligands. In the crystal structure, weak C-H⋯S and π-π stacking interactions form chains of rings.

AB - In the title molecule, [Na(C5H10NS 2)(C12H8N2)2], which has crystallographic twofold symmetry, the coordination geometry of the Na atom is intermediate between octahedral and trigonal prismatic, coordinated by two S atoms of an N,N-diethyldithiocarbamate ligand and four chelating N atoms of two 1,10-phenanthroline ligands. In the crystal structure, weak C-H⋯S and π-π stacking interactions form chains of rings.

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