Nickel-Gallium-Catalyzed Electrochemical Reduction of CO2 to Highly Reduced Products at Low Overpotentials

Daniel A. Torelli, Sonja A. Francis, J. Chance Crompton, Alnald Javier, Jonathan R. Thompson, Bruce S. Brunschwig, Manuel P. Soriaga, Nathan S. Lewis

Research output: Contribution to journalArticlepeer-review

243 Scopus citations


We report the electrocatalytic reduction of CO2 to the highly reduced C2 products, ethylene and ethane, as well as to the fully reduced C1 product, methane, on three different phases of nickel-gallium (NiGa, Ni3Ga, and Ni5Ga3) films prepared by drop-casting. In aqueous bicarbonate electrolytes at neutral pH, the onset potential for methane, ethylene, and ethane production on all three phases was found to be -0.48 V versus the reversible hydrogen electrode (RHE), among the lowest onset potentials reported to date for the production of C2 products from CO2. Similar product distributions and onset potentials were observed for all three nickel-gallium stoichiometries tested. The onset potential for the reduction of CO2 to C2 products at low current densities catalyzed by nickel-gallium was >250 mV more positive than that of polycrystalline copper, and approximately equal to that of single crystals of copper, which have some of the lowest overpotentials to date for the reduction of CO2 to C2 products and methane. The nickel-gallium films also reduced CO to ethylene, ethane, and methane, consistent with a CO2 reduction mechanism that first involves the reduction of CO2 to CO. Isotopic labeling experiments with 13CO2 confirmed that the detected products were produced exclusively by the reduction of CO2.

Original languageEnglish (US)
Pages (from-to)2100-2104
Number of pages5
JournalACS Catalysis
Issue number3
StatePublished - Mar 4 2016
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • General Chemistry


  • C2 production
  • CO reduction
  • NiGa
  • electrocatalysis
  • ethane
  • low overpotential
  • methane
  • nickel gallium


Dive into the research topics of 'Nickel-Gallium-Catalyzed Electrochemical Reduction of CO2 to Highly Reduced Products at Low Overpotentials'. Together they form a unique fingerprint.

Cite this