Nematic solvation of segmented polymer chains

S. Link, D. Hu, W. S. Chang, G. D. Scholes, P. F. Barbara

Research output: Contribution to journalArticlepeer-review

19 Scopus citations


We examine the effect of polymer chain segmentation on the recently discovered ability of nematic solvents to elongate and align polymer chain solutes. Coordinated single molecule spectroscopy and beads-on-a-chain simulations are used to study the orientational and conformational order of a series of segmented conjugated polymers, dissolved in the nematic liquid crystal 5CB. The order parameters for alignment and elongation are both observed to decrease with increasing segmentation, reflecting an interplay among conformational entropy, solvation anisotropy, and bending energy of the chain.

Original languageEnglish (US)
Pages (from-to)1757-1760
Number of pages4
JournalNano Letters
Issue number9
StatePublished - Sep 1 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering


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