Nanospectroscopy Captures Nanoscale Compositional Zonation in Barite Solid Solutions

Florence T. Ling, Heather A. Hunter, Jeffrey P. Fitts, Catherine Anne Peters, Alvin S. Acerbo, Xiaojing Huang, Hanfei Yan, Evgeny Nazaretski, Yong S. Chu

Research output: Contribution to journalArticlepeer-review

23 Scopus citations


Scientists have long suspected that compositionally zoned particles can form under far-from equilibrium precipitation conditions, but their inferences have been based on bulk solid and solution measurements. We are the first to directly observe nanoscale trace element compositional zonation in <10 µm-sized particles using X-ray fluorescence nanospectroscopy at the Hard X-ray Nanoprobe (HXN) Beamline at National Synchrotron Light Source II (NSLS-II). Through high-resolution images, compositional zonation was observed in barite (BaSO4) particles precipitated from aqueous solution, in which Sr2+ cations as well as HAsO4 2− anions were co-precipitated into (Ba,Sr)SO4 or Ba(SO4,HAsO4) solid solutions. Under high salinity conditions (NaCl ≥ 1.0 M), bands contained ~3.5 to ~5 times more trace element compared to the center of the particle formed in early stages of particle growth. Quantitative analysis of Sr and As fractional substitution allowed us to determine that different crystallographic growth directions incorporated trace elements to different extents. These findings provide supporting evidence that barite solid solutions have great potential for trace element incorporation; this has significant implications for environmental and engineered systems that remove hazardous substances from water.

Original languageEnglish (US)
Article number13041
JournalScientific reports
Issue number1
StatePublished - Dec 1 2018

All Science Journal Classification (ASJC) codes

  • General


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