Morphological Variation at the [NiFe(CN)6]2-/-Derivatized Nickel Electrode: A Technique for the Evaluation of Alkali Cation Containing Solutions

Linda J. Amos; Anil Duggal; Eric J. Mirsky; Peter Ragonesi; Andrew Bruce Bocarsly; Patricia A. Fitzgerald-Bocarsly

doi:10.1021/ac00154a012

Morphological Variation at the [NiFe(CN)₆]^2-/-Derivatized Nickel Electrode: A Technique for the Evaluation of Alkali Cation Containing Solutions

Linda J. Amos, Anil Duggal, Eric J. Mirsky, Peter Ragonesi, Andrew Bruce Bocarsly, Patricia A. Fitzgerald-Bocarsly

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Abstract

Sensitive and analytically useful detection of alkali cations is possible by cyclic voltammetry using a [NIFe(CN)₈]^2-/- derivatized nickel working electrode. The mechanism of detection is based on microstructure variations in the [NIFe(CN)₆]^2-/- lattice. As such this derivatized electrode system represents a new mechanism of electrochemical detection, allowing for the voltammetric detection of species which are not electroactive. Thus, the Indicated approach is novel in that it provides a mechanism for Identifying different alkali cations by cyclic voltammetry. The capabilities of this system are Illustrated by using electrolytes containing sodium and cesium cations. For this case It is found that as little as 10^-8M CsNO₃can be analytically detected In the presence of 1 M NaNO₃.

Original language	English (US)
Pages (from-to)	245-249
Number of pages	5
Journal	Analytical Chemistry
Volume	60
Issue number	3
DOIs	https://doi.org/10.1021/ac00154a012
State	Published - Feb 1 1988

All Science Journal Classification (ASJC) codes

Analytical Chemistry

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title = "Morphological Variation at the [NiFe(CN)6]2-/-Derivatized Nickel Electrode: A Technique for the Evaluation of Alkali Cation Containing Solutions",

abstract = "Sensitive and analytically useful detection of alkali cations is possible by cyclic voltammetry using a [NIFe(CN)8]2-/- derivatized nickel working electrode. The mechanism of detection is based on microstructure variations in the [NIFe(CN)6]2-/- lattice. As such this derivatized electrode system represents a new mechanism of electrochemical detection, allowing for the voltammetric detection of species which are not electroactive. Thus, the Indicated approach is novel in that it provides a mechanism for Identifying different alkali cations by cyclic voltammetry. The capabilities of this system are Illustrated by using electrolytes containing sodium and cesium cations. For this case It is found that as little as 10-8M CsNO3can be analytically detected In the presence of 1 M NaNO3.",

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T2 - A Technique for the Evaluation of Alkali Cation Containing Solutions

AU - Amos, Linda J.

AU - Duggal, Anil

AU - Mirsky, Eric J.

AU - Ragonesi, Peter

AU - Bocarsly, Andrew Bruce

AU - Fitzgerald-Bocarsly, Patricia A.

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N2 - Sensitive and analytically useful detection of alkali cations is possible by cyclic voltammetry using a [NIFe(CN)8]2-/- derivatized nickel working electrode. The mechanism of detection is based on microstructure variations in the [NIFe(CN)6]2-/- lattice. As such this derivatized electrode system represents a new mechanism of electrochemical detection, allowing for the voltammetric detection of species which are not electroactive. Thus, the Indicated approach is novel in that it provides a mechanism for Identifying different alkali cations by cyclic voltammetry. The capabilities of this system are Illustrated by using electrolytes containing sodium and cesium cations. For this case It is found that as little as 10-8M CsNO3can be analytically detected In the presence of 1 M NaNO3.

AB - Sensitive and analytically useful detection of alkali cations is possible by cyclic voltammetry using a [NIFe(CN)8]2-/- derivatized nickel working electrode. The mechanism of detection is based on microstructure variations in the [NIFe(CN)6]2-/- lattice. As such this derivatized electrode system represents a new mechanism of electrochemical detection, allowing for the voltammetric detection of species which are not electroactive. Thus, the Indicated approach is novel in that it provides a mechanism for Identifying different alkali cations by cyclic voltammetry. The capabilities of this system are Illustrated by using electrolytes containing sodium and cesium cations. For this case It is found that as little as 10-8M CsNO3can be analytically detected In the presence of 1 M NaNO3.

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Morphological Variation at the [NiFe(CN)₆]^2-/-Derivatized Nickel Electrode: A Technique for the Evaluation of Alkali Cation Containing Solutions

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