Abstract
Polymer layered silicates form an important class of nanocomposite materials. During their formation by melt intercalation, polymer molecules from a bulk fluid move into the galleries of layered silicates. An essential feature of this process is the flow of macromolecules from a bulk fluid to a confined environment. To model this phenomenon, we have performed molecular dynamics simulations of the flow of polymer molecules from a bulk melt into a rectangular slit. The simulations are consistent with a diffusive description of the transport, and show qualitative agreement with time-dependent x-ray diffraction measurements of intercalation kinetics in layered nanocomposites.
Original language | English (US) |
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Pages (from-to) | 131-135 |
Number of pages | 5 |
Journal | Materials Research Society Symposium - Proceedings |
Volume | 543 |
State | Published - 1999 |
Externally published | Yes |
Event | Proceedings of the 1998 MRS Fall Meeting - The Symposium 'Advanced Catalytic Materials-1998' - Boston, MA, USA Duration: Nov 30 1998 → Dec 3 1998 |
All Science Journal Classification (ASJC) codes
- General Materials Science
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering