Mn2(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A microporous metal-organic framework with infinite (-Mn-S-)∞ chains and high intrinsic charge mobility

Lei Sun; Tomoyo Miyakai; Shu Seki; Mircea Dincǎ

doi:10.1021/ja4037516

Mn₂(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A microporous metal-organic framework with infinite (-Mn-S-)_∞ chains and high intrinsic charge mobility

Lei Sun, Tomoyo Miyakai, Shu Seki, Mircea Dincǎ

Research output: Contribution to journal › Article › peer-review

309 Scopus citations

Abstract

The reaction of MnCl₂ with 2,5-disulfhydrylbenzene-1,4- dicarboxylic acid (H₄DSBDC), in which the phenol groups in 2,5-dihydroxybenzene-1,4-dicarboxylic acid (H₄DOBDC) have been replaced by thiophenol units, led to the isolation of Mn₂(DSBDC), a thiolated analogue of the M₂(DOBDC) series of metal-organic frameworks (MOFs). The sulfur atoms participate in infinite one-dimensional Mn-S chains, and Mn₂(DSBDC) shows a high surface area and high charge mobility similar to that found in some of the most common organic semiconductors. The synthetic approach to Mn₂(DSBDC) and its excellent electronic properties provide a blueprint for a potentially rich area of exploration in microporous conductive MOFs with low-dimensional charge transport pathways.

Original language	English (US)
Pages (from-to)	8185-8188
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	22
DOIs	https://doi.org/10.1021/ja4037516
State	Published - Jun 5 2013
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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title = "Mn2(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A microporous metal-organic framework with infinite (-Mn-S-)∞ chains and high intrinsic charge mobility",

abstract = "The reaction of MnCl2 with 2,5-disulfhydrylbenzene-1,4- dicarboxylic acid (H4DSBDC), in which the phenol groups in 2,5-dihydroxybenzene-1,4-dicarboxylic acid (H4DOBDC) have been replaced by thiophenol units, led to the isolation of Mn2(DSBDC), a thiolated analogue of the M2(DOBDC) series of metal-organic frameworks (MOFs). The sulfur atoms participate in infinite one-dimensional Mn-S chains, and Mn2(DSBDC) shows a high surface area and high charge mobility similar to that found in some of the most common organic semiconductors. The synthetic approach to Mn2(DSBDC) and its excellent electronic properties provide a blueprint for a potentially rich area of exploration in microporous conductive MOFs with low-dimensional charge transport pathways.",

author = "Lei Sun and Tomoyo Miyakai and Shu Seki and Mircea Dincǎ",

year = "2013",

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doi = "10.1021/ja4037516",

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T2 - A microporous metal-organic framework with infinite (-Mn-S-)∞ chains and high intrinsic charge mobility

AU - Sun, Lei

AU - Miyakai, Tomoyo

AU - Seki, Shu

AU - Dincǎ, Mircea

PY - 2013/6/5

Y1 - 2013/6/5

N2 - The reaction of MnCl2 with 2,5-disulfhydrylbenzene-1,4- dicarboxylic acid (H4DSBDC), in which the phenol groups in 2,5-dihydroxybenzene-1,4-dicarboxylic acid (H4DOBDC) have been replaced by thiophenol units, led to the isolation of Mn2(DSBDC), a thiolated analogue of the M2(DOBDC) series of metal-organic frameworks (MOFs). The sulfur atoms participate in infinite one-dimensional Mn-S chains, and Mn2(DSBDC) shows a high surface area and high charge mobility similar to that found in some of the most common organic semiconductors. The synthetic approach to Mn2(DSBDC) and its excellent electronic properties provide a blueprint for a potentially rich area of exploration in microporous conductive MOFs with low-dimensional charge transport pathways.

AB - The reaction of MnCl2 with 2,5-disulfhydrylbenzene-1,4- dicarboxylic acid (H4DSBDC), in which the phenol groups in 2,5-dihydroxybenzene-1,4-dicarboxylic acid (H4DOBDC) have been replaced by thiophenol units, led to the isolation of Mn2(DSBDC), a thiolated analogue of the M2(DOBDC) series of metal-organic frameworks (MOFs). The sulfur atoms participate in infinite one-dimensional Mn-S chains, and Mn2(DSBDC) shows a high surface area and high charge mobility similar to that found in some of the most common organic semiconductors. The synthetic approach to Mn2(DSBDC) and its excellent electronic properties provide a blueprint for a potentially rich area of exploration in microporous conductive MOFs with low-dimensional charge transport pathways.

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Mn₂(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A microporous metal-organic framework with infinite (-Mn-S-)_∞ chains and high intrinsic charge mobility

Abstract

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