Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

Larry I. Shoer; Kerrie I. Gell; Jeffrey Schwartz

doi:10.1016/S0022-328X(00)82126-9

Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

Larry I. Shoer
, Kerrie I. Gell
, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Dialkylaluminum hydrides and Cp₂ZrX₂ (Cp = π⁵-C₅H₅; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.

Original language	English (US)
Pages (from-to)	c19-c22
Journal	Journal of Organometallic Chemistry
Volume	136
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)82126-9
State	Published - Aug 23 1977

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(00)82126-9

Cite this

@article{501a2d3fd29a4f68820f84ffb3bae479,

title = "Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides",

abstract = "Dialkylaluminum hydrides and Cp2ZrX2 (Cp = π5-C5H5; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.",

author = "Shoer, \{Larry I.\} and Gell, \{Kerrie I.\} and Jeffrey Schwartz",

note = "Funding Information: The authors acknowfedge generous support for this work given by the National Science Foundation (CI-E 76-02130).",

year = "1977",

month = aug,

day = "23",

doi = "10.1016/S0022-328X(00)82126-9",

language = "English (US)",

volume = "136",

pages = "c19--c22",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

AU - Shoer, Larry I.

AU - Gell, Kerrie I.

AU - Schwartz, Jeffrey

N1 - Funding Information: The authors acknowfedge generous support for this work given by the National Science Foundation (CI-E 76-02130).

PY - 1977/8/23

Y1 - 1977/8/23

N2 - Dialkylaluminum hydrides and Cp2ZrX2 (Cp = π5-C5H5; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.

AB - Dialkylaluminum hydrides and Cp2ZrX2 (Cp = π5-C5H5; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.

UR - https://www.scopus.com/pages/publications/0007724305

UR - https://www.scopus.com/pages/publications/0007724305#tab=citedBy

U2 - 10.1016/S0022-328X(00)82126-9

DO - 10.1016/S0022-328X(00)82126-9

M3 - Article

AN - SCOPUS:0007724305

SN - 0022-328X

VL - 136

SP - c19-c22

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this