Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

Larry I. Shoer; Kerrie I. Gell; Jeffrey Schwartz

doi:10.1016/S0022-328X(00)82126-9

Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

Larry I. Shoer, Kerrie I. Gell, Jeffrey Schwartz

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Abstract

Dialkylaluminum hydrides and Cp₂ZrX₂ (Cp = π⁵-C₅H₅; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.

Original language	English (US)
Pages (from-to)	c19-c22
Journal	Journal of Organometallic Chemistry
Volume	136
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)82126-9
State	Published - Aug 23 1977

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)82126-9

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title = "Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides",

abstract = "Dialkylaluminum hydrides and Cp2ZrX2 (Cp = π5-C5H5; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.",

author = "Shoer, {Larry I.} and Gell, {Kerrie I.} and Jeffrey Schwartz",

note = "Funding Information: The authors acknowfedge generous support for this work given by the National Science Foundation (CI-E 76-02130).",

year = "1977",

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doi = "10.1016/S0022-328X(00)82126-9",

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T1 - Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

AU - Shoer, Larry I.

AU - Gell, Kerrie I.

AU - Schwartz, Jeffrey

N1 - Funding Information: The authors acknowfedge generous support for this work given by the National Science Foundation (CI-E 76-02130).

PY - 1977/8/23

Y1 - 1977/8/23

N2 - Dialkylaluminum hydrides and Cp2ZrX2 (Cp = π5-C5H5; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.

AB - Dialkylaluminum hydrides and Cp2ZrX2 (Cp = π5-C5H5; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.

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U2 - 10.1016/S0022-328X(00)82126-9

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SP - c19-c22

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

Abstract

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