Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

Larry I. Shoer, Kerrie I. Gell, Jeffrey Schwartz

Research output: Contribution to journalArticle

36 Scopus citations

Abstract

Dialkylaluminum hydrides and Cp2ZrX2 (Cp = π5-C5H5; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn.

Original languageEnglish (US)
Pages (from-to)c19-c22
JournalJournal of Organometallic Chemistry
Volume136
Issue number2
DOIs
StatePublished - Aug 23 1977

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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