Microstructural stability of supported metal catalysts: A phase field approach

Ryan Davis, Mikko Haataja

Research output: Contribution to journalArticle

2 Scopus citations

Abstract

The long-term stability of supported metal catalysts designed for solid-oxide fuel cell (SOFC) anodes is evaluated using a phase field simulation approach. Porous support structures are numerically sintered and then infiltrated with a nanoscale catalyst phase to mimic scaffolds fabricated via both pyrolysis and acid leaching techniques. Simulations capture the dewetting, particle agglomeration, and coarsening processes that occur during extended operation at elevated temperatures. We systematically explore the microstructural evolution of the active phase for a range of infiltration loadings from 2 to 21% and report on common performance metrics, such as triple phase boundary (TPB) density and contiguity. Ostwald ripening and particle migration and coalescence events are identified as dominant mechanisms contributing to severe reductions in the TPB density and catalyst deactivation. Despite marked differences between the simulated pyrolyzed and leached scaffold structures, the resulting TPB densities are comparable in value. Additionally, we show that tuning the metal catalyst/scaffold contact angle between 60 and 120 does not significantly affect TPB density. More broadly, this work elucidates the challenges associated with stabilizing nanoscale dispersions prepared by infiltration and similar techniques.

Original languageEnglish (US)
Pages (from-to)111-121
Number of pages11
JournalJournal of Power Sources
Volume369
DOIs
StatePublished - 2017

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Keywords

  • Catalyst
  • Infiltration
  • Phase field
  • SOFC
  • Sintering
  • Triple phase boundary

Fingerprint Dive into the research topics of 'Microstructural stability of supported metal catalysts: A phase field approach'. Together they form a unique fingerprint.

Cite this