@article{f79f046abdca466ebe8de2bd8fd62655,
title = "Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis",
abstract = "The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the broad utility of photoinduced electron- and energy-transfer processes. Photocatalytic substrate activation has allowed the engagement of simple starting materials in metal-mediated bond-forming processes. Moreover, electron or energy transfer directly with key organometallic intermediates has provided novel activation modes entirely complementary to traditional catalytic platforms. This Review details and contextualizes the advancements in molecule construction brought forth by metallaphotocatalysis.",
author = "Chan, {Amy Y.} and Perry, {Ian B.} and Bissonnette, {Noah B.} and Buksh, {Benito F.} and Edwards, {Grant A.} and Frye, {Lucas I.} and Garry, {Olivia L.} and Lavagnino, {Marissa N.} and Li, {Beryl X.} and Yufan Liang and Edna Mao and Agustin Millet and Oakley, {James V.} and Reed, {Nicholas L.} and Sakai, {Holt A.} and Seath, {Ciaran P.} and MacMillan, {David W.C.}",
note = "Funding Information: The authors are grateful for financial support provided by the National Institute of General Medical Sciences (NIGMS), the NIH (under Award R35GM134897-01), the Princeton Catalysis Initiative, and kind gifts from Merck, Janssen, BMS, Genentech, Celgene, and Pfizer. N.B.B., L.I.F., and E.M. acknowledge Princeton University for first-year fellowships. A.Y.C., B.F.B., O.L.G., J.V.O., and H.A.S. acknowledge Princeton University, E. Taylor, and the Taylor family for an Edward C. Taylor Fellowship. J.V.O. acknowledges the NSF for a predoctoral fellowship (DGE-1656466). B.X.L. and A.M. acknowledge support from BioLEC, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science under Award No. DE-SC0019370. We thank Vlad Bacauanu, Nathan W. Dow, Patrick J. Sarver, and Dr. Mario P. Wiesenfeldt for their assistance in preparing this manuscript. Publisher Copyright: {\textcopyright} 2021 American Chemical Society",
year = "2022",
month = jan,
day = "26",
doi = "10.1021/acs.chemrev.1c00383",
language = "English (US)",
volume = "122",
pages = "1485--1542",
journal = "Chemical Reviews",
issn = "0009-2665",
publisher = "American Chemical Society",
number = "2",
}