Merging photoredox catalysis with organocatalysis: The direct asymmetric alkylation of aldehydes

Keyphrases

• Organocatalysis 100%
• Alkylation 100%
• Photoredox-catalyzed 100%
• Ru(bpy)32+ 100%
• Alkylation of Aldehydes 100%
• Asymmetric Alkylation 100%
• Light Source 80%
• Organocatalytic 80%
• Electron-deficient 60%
• Enantioselectivity 60%
• Aldehydes 60%
• Catalytic Cycle 60%
• Enamines 60%
• Photoredox 40%
• Single Electron Transfer 40%
• Imidazolidinone 40%
• 2-cycles 40%
• Ru(bpy)3 40%
• Functional Groups 20%
• Excellent Yields 20%
• Chemical Synthesis 20%
• Operative 20%
• Absorption Bands 20%
• Overall Rate 20%
• Bond Homolysis 20%
• Condensation 20%
• Electron-rich 20%
• Dual Cocatalysts 20%
• Organic Chemistry 20%
• Alkyl Radicals 20%
• Enantioenriched 20%
• Redox Conditions 20%
• Molecular Activation 20%
• Catalytic Alkylation 20%
• Iminium Ion 20%
• Bulky Groups 20%
• Photon Source 20%
• Octanal 20%
• Electron Transfer Catalysis 20%
• Amino Radical 20%
• Tandem Catalysis 20%
• Alkylating Agents 20%
• Photolytic 20%
• Organic Catalysis 20%
• Dual Cycle 20%
• Si-face 20%
• MLCT Absorptions 20%
• Inorganic Chemistry 20%
• Fluorescent Light 20%
• Electron-rich Ru 20%
• High Energy Intermediates 20%

Chemistry

• Photoredox Catalysis 100%
• Organocatalysis 100%
• Alkylation 100%
• Aldehyde 100%
• Enamine 50%
• Electron Transport 50%
• catalytic cycle 50%
• Photoredox 33%
• Enantioselectivity 33%
• Imidazolidinone 33%
• Catalysis 33%
• Catalyst 33%
• Organic Chemistry 16%
• Catalytic Alkylation 16%
• Iminium Ion 16%
• Octanal 16%
• Condensation 16%
• Redox Condition 16%
• Alkylating Agent 16%
• Inorganic Chemistry 16%
• Enzymatic Hydrolysis 16%
• Absorption Spectra 16%
• Hydrolysis 16%