Mechanistic studies of an unusual epoxide-forming elimination of a β-hydroxyalkyl rhodium porphyrin

Yuan Zhang Han; Melanie S. Sanford; Michael D. England; John Taylor Groves

doi:10.1039/b511974j

Mechanistic studies of an unusual epoxide-forming elimination of a β-hydroxyalkyl rhodium porphyrin

Yuan Zhang Han
, Melanie S. Sanford
, Michael D. England
, John Taylor Groves

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A new and remarkably facile sp³-C-O bond forming reaction of β-hydroxyalkyl Rh porphyrins to form epoxides has been discovered and its mechanism investigated.

Original language	English (US)
Pages (from-to)	549-551
Number of pages	3
Journal	Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/b511974j
State	Published - 2006

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/b511974j

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title = "Mechanistic studies of an unusual epoxide-forming elimination of a β-hydroxyalkyl rhodium porphyrin",

abstract = "A new and remarkably facile sp3-C-O bond forming reaction of β-hydroxyalkyl Rh porphyrins to form epoxides has been discovered and its mechanism investigated.",

author = "Han, \{Yuan Zhang\} and Sanford, \{Melanie S.\} and England, \{Michael D.\} and Groves, \{John Taylor\}",

year = "2006",

doi = "10.1039/b511974j",

language = "English (US)",

pages = "549--551",

journal = "Chemical Communications",

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AU - Han, Yuan Zhang

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AU - England, Michael D.

AU - Groves, John Taylor

PY - 2006

Y1 - 2006

N2 - A new and remarkably facile sp3-C-O bond forming reaction of β-hydroxyalkyl Rh porphyrins to form epoxides has been discovered and its mechanism investigated.

AB - A new and remarkably facile sp3-C-O bond forming reaction of β-hydroxyalkyl Rh porphyrins to form epoxides has been discovered and its mechanism investigated.

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JO - Chemical Communications

JF - Chemical Communications

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Mechanistic studies of an unusual epoxide-forming elimination of a β-hydroxyalkyl rhodium porphyrin

Abstract

All Science Journal Classification (ASJC) codes

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