Mechanistic aspects of (CC) isomerization in vinylic rhodium(III) complexes

Donald W. Hart; Jeffrey Schwartz

doi:10.1016/S0022-328X(00)80353-8

Mechanistic aspects of (CC) isomerization in vinylic rhodium(III) complexes

Donald W. Hart, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Observations concerning the (CC) isomerization of several vinylic Rh^III complexes suggest an intramolecular pathway; isomerization occurs at a rate which is affected by the backbonding ability of the metal and the π-acidity of the vinylic ligand in the complex.

Original language	English (US)
Pages (from-to)	C11-C14
Journal	Journal of Organometallic Chemistry
Volume	87
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)80353-8
State	Published - Mar 11 1975

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)80353-8

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title = "Mechanistic aspects of (CC) isomerization in vinylic rhodium(III) complexes",

abstract = "Observations concerning the (CC) isomerization of several vinylic RhIII complexes suggest an intramolecular pathway; isomerization occurs at a rate which is affected by the backbonding ability of the metal and the π-acidity of the vinylic ligand in the complex.",

author = "Hart, \{Donald W.\} and Jeffrey Schwartz",

year = "1975",

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doi = "10.1016/S0022-328X(00)80353-8",

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T1 - Mechanistic aspects of (CC) isomerization in vinylic rhodium(III) complexes

AU - Hart, Donald W.

AU - Schwartz, Jeffrey

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Y1 - 1975/3/11

N2 - Observations concerning the (CC) isomerization of several vinylic RhIII complexes suggest an intramolecular pathway; isomerization occurs at a rate which is affected by the backbonding ability of the metal and the π-acidity of the vinylic ligand in the complex.

AB - Observations concerning the (CC) isomerization of several vinylic RhIII complexes suggest an intramolecular pathway; isomerization occurs at a rate which is affected by the backbonding ability of the metal and the π-acidity of the vinylic ligand in the complex.

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U2 - 10.1016/S0022-328X(00)80353-8

DO - 10.1016/S0022-328X(00)80353-8

M3 - Article

AN - SCOPUS:0010149951

SN - 0022-328X

VL - 87

SP - C11-C14

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Mechanistic aspects of (CC) isomerization in vinylic rhodium(III) complexes

Abstract

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