Mechanistic aspects of (CC) isomerization in vinylic rhodium(III) complexes

Donald W. Hart, Jeffrey Schwartz

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Observations concerning the (CC) isomerization of several vinylic RhIII complexes suggest an intramolecular pathway; isomerization occurs at a rate which is affected by the backbonding ability of the metal and the π-acidity of the vinylic ligand in the complex.

Original languageEnglish (US)
Pages (from-to)C11-C14
JournalJournal of Organometallic Chemistry
Issue number1
StatePublished - Mar 11 1975

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry


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