Mechanism of the oxidation of alcohols by 2,2,6,6-tetramethylpiperidine nitrosonium cation

Martin F. Semmelhack, Christopher R. Schmid, David A. Cortés

Research output: Contribution to journalArticlepeer-review

130 Scopus citations

Abstract

Simple Hammett studies, hydrogen isotope effects, and attempted preparation of proposed transient intermediates are used to probe the mechanism of oxidation of alcohols by 2,2,6,6-tetramethylpiperidine nitrosonium ion.

Original languageEnglish (US)
Pages (from-to)1119-1122
Number of pages4
JournalTetrahedron Letters
Volume27
Issue number10
DOIs
StatePublished - Jan 1 1986

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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