Materials challenges in reverse-flow pyrolysis reactors for petrochemical applications

Chang Min Chun, Sanket Desai, Frank Hershkowitz, Paul F. Keusenkothen, Gary D. Mohr, Trikur A. Ramanarayanan

Research output: Contribution to journalArticlepeer-review

3 Scopus citations


Currently, the pyrolysis of hydrocarbons for the production of light olefins is almost exclusively carried out in steam crackers operating around 900-1000°C. However, cracking hydrocarbons at much higher temperature results in high selectivity to acetylene, which can be converted into many petrochemical products including ethylene. The desired hydropyrolysis reaction from hydrocarbons to acetylene can be realized in a reverse-flow reactor at very high temperatures (>1700°C) in a scalable manner. The reactor elements include ceramic components that are placed in the hottest regions of the reactor and must withstand a temperature that is in the range of 1500-2000°C. In addition, the temperature rises and falls with the reverse-flow cycle; a fluctuation that could be as high as 100-500°C over a period of several seconds. Moreover, the materials in the hot zone are exposed alternately to a regeneration (heat addition) step that is mildly oxidizing, and a pyrolysis (cracking) step that is strongly reducing with a correspondingly high carbon activity. This article addresses the thermodynamic stability of selected ceramic materials based on alumina, zirconia, and yttria for such an application. Results from laboratory tests involving the exposure of these ceramic materials to simulated process conditions followed by their microstructural characterization are compared with expectations from thermodynamic predictions.

Original languageEnglish (US)
Pages (from-to)106-117
Number of pages12
JournalInternational Journal of Applied Ceramic Technology
Issue number1
StatePublished - Jan 2014

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Condensed Matter Physics
  • Marketing
  • Materials Chemistry


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