Manganese porphyrins catalyze selective C-H bond halogenations

Engineering & Materials Science

• Halogenation 100%
• Porphyrins 88%
• Chlorination 75%
• Manganese 59%
• Substrates 30%
• Sodium 21%
• Regioselectivity 14%
• Catalysts 12%
• Carbon 10%
• Oxygenation 10%
• Free radicals 10%
• Chlorine 8%
• Paraffins 8%
• Atoms 7%
• Hydrogen 5%
• Geometry 4%

Medicine & Life Sciences

• Halogenation 66%
• Porphyrins 64%
• Manganese 60%
• Sodium Hypochlorite 28%
• Chlorides 22%
• norcarane 18%
• neopentane 17%
• sclareolide 16%
• Carbon 14%
• decalin 13%
• pentabrominated diphenyl ether 100 13%
• Cholestanes 12%
• Thymidine Monophosphate 10%
• Alkanes 10%
• Chlorine 9%
• Hydrogen 8%
• Free Radicals 6%
• chloro(5,10,15,20-tetraphenylporphyrinato)manganese(III) 1%

Chemical Compounds

• Sodium Hypochlorite 47%
• Porphyrin 42%
• Chloride 21%
• Trans-Decalin 19%
• Neopentane 18%
• Reaction Yield 15%
• Phase-Transfer Catalyst 14%
• Aryl Group 14%
• Oxygenation 13%
• Frontier Orbital 13%
• Alkyl Group 12%
• Regioselectivity 11%
• Carbon Atom 11%
• Hydrogen Atom 10%
• Chlorine 10%
• Amount 10%
• Alkane 10%
• Catalyst 5%