Macroscopic orientation of block copolymer cylinders in single-layer films by shearing

Dan E. Angelescu; Judith H. Waller; Douglas H. Adamson; Paru Deshpande; Stephen Y. Chou; Richard A. Register; Paul M. Chaikin

doi:10.1002/adma.200400643

Macroscopic orientation of block copolymer cylinders in single-layer films by shearing

Dan E. Angelescu, Judith H. Waller, Douglas H. Adamson, Paru Deshpande, Stephen Y. Chou, Richard A. Register, Paul M. Chaikin

Research output: Contribution to journal › Article › peer-review

317 Scopus citations

Abstract

The shearing method, which was used for the macroscopic orientation of block copolymer cylinders in single-layer films, was discussed. It was found that the shearing technique provides a simple, scalable pathway to single-layer copolymer alignment. Shearing can induce both ordering and disordering in concentrated solutions of cylinder-forming diblocks. The results show that the shearing technique also prove a useful tool for fundamental studies of linear and nonlinear viscosity, elasticity, shear melting and alignment in a well controlled and constrained geometry.

Original language	English (US)
Pages (from-to)	1736-1740
Number of pages	5
Journal	Advanced Materials
Volume	16
Issue number	19
DOIs	https://doi.org/10.1002/adma.200400643
State	Published - Oct 4 2004

All Science Journal Classification (ASJC) codes

General Materials Science
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1002/adma.200400643

Cite this

@article{6497a76afd71499d8b31221776de1f1a,

title = "Macroscopic orientation of block copolymer cylinders in single-layer films by shearing",

abstract = "The shearing method, which was used for the macroscopic orientation of block copolymer cylinders in single-layer films, was discussed. It was found that the shearing technique provides a simple, scalable pathway to single-layer copolymer alignment. Shearing can induce both ordering and disordering in concentrated solutions of cylinder-forming diblocks. The results show that the shearing technique also prove a useful tool for fundamental studies of linear and nonlinear viscosity, elasticity, shear melting and alignment in a well controlled and constrained geometry.",

author = "Angelescu, {Dan E.} and Waller, {Judith H.} and Adamson, {Douglas H.} and Paru Deshpande and Chou, {Stephen Y.} and Register, {Richard A.} and Chaikin, {Paul M.}",

year = "2004",

month = oct,

day = "4",

doi = "10.1002/adma.200400643",

language = "English (US)",

volume = "16",

pages = "1736--1740",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-VCH Verlag",

number = "19",

}

TY - JOUR

T1 - Macroscopic orientation of block copolymer cylinders in single-layer films by shearing

AU - Angelescu, Dan E.

AU - Waller, Judith H.

AU - Adamson, Douglas H.

AU - Deshpande, Paru

AU - Chou, Stephen Y.

AU - Register, Richard A.

AU - Chaikin, Paul M.

PY - 2004/10/4

Y1 - 2004/10/4

N2 - The shearing method, which was used for the macroscopic orientation of block copolymer cylinders in single-layer films, was discussed. It was found that the shearing technique provides a simple, scalable pathway to single-layer copolymer alignment. Shearing can induce both ordering and disordering in concentrated solutions of cylinder-forming diblocks. The results show that the shearing technique also prove a useful tool for fundamental studies of linear and nonlinear viscosity, elasticity, shear melting and alignment in a well controlled and constrained geometry.

AB - The shearing method, which was used for the macroscopic orientation of block copolymer cylinders in single-layer films, was discussed. It was found that the shearing technique provides a simple, scalable pathway to single-layer copolymer alignment. Shearing can induce both ordering and disordering in concentrated solutions of cylinder-forming diblocks. The results show that the shearing technique also prove a useful tool for fundamental studies of linear and nonlinear viscosity, elasticity, shear melting and alignment in a well controlled and constrained geometry.

UR - http://www.scopus.com/inward/record.url?scp=9144247901&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=9144247901&partnerID=8YFLogxK

U2 - 10.1002/adma.200400643

DO - 10.1002/adma.200400643

M3 - Article

AN - SCOPUS:9144247901

SN - 0935-9648

VL - 16

SP - 1736

EP - 1740

JO - Advanced Materials

JF - Advanced Materials

IS - 19

ER -

Macroscopic orientation of block copolymer cylinders in single-layer films by shearing

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this