Low-Dimensional VS3Synthesized at Elevated Pressure

Danrui Ni; Guangming Cheng; Stephen Zhang; Ruyi Ke; Nan Yao; R. J. Cava

doi:10.1021/acs.inorgchem.5c04356

Low-Dimensional VS₃Synthesized at Elevated Pressure

Danrui Ni
, Guangming Cheng
, Stephen Zhang
, Ruyi Ke
, Nan Yao
, R. J. Cava

Research output: Contribution to journal › Article › peer-review

Abstract

VS₃, a transition metal trichalcogenide that has not been previously reported, was successfully prepared by a high-pressure solid-state synthesis method. Its low-dimensional crystal structure, refined by Rietveld PXRD and confirmed by HR-STEM, features both uncommon V–S coordination polyhedra and S–S dimers. Preliminary characterization reveals low-moment paramagnetic behavior and a semiconducting nature.

Original language	English (US)
Pages (from-to)	22174-22181
Number of pages	8
Journal	Inorganic Chemistry
Volume	64
Issue number	44
DOIs	https://doi.org/10.1021/acs.inorgchem.5c04356
State	Published - Nov 10 2025

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/acs.inorgchem.5c04356

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title = "Low-Dimensional VS3Synthesized at Elevated Pressure",

abstract = "VS3, a transition metal trichalcogenide that has not been previously reported, was successfully prepared by a high-pressure solid-state synthesis method. Its low-dimensional crystal structure, refined by Rietveld PXRD and confirmed by HR-STEM, features both uncommon V–S coordination polyhedra and S–S dimers. Preliminary characterization reveals low-moment paramagnetic behavior and a semiconducting nature.",

author = "Danrui Ni and Guangming Cheng and Stephen Zhang and Ruyi Ke and Nan Yao and Cava, \{R. J.\}",

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journal = "Inorganic Chemistry",

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AU - Ni, Danrui

AU - Cheng, Guangming

AU - Zhang, Stephen

AU - Ke, Ruyi

AU - Yao, Nan

AU - Cava, R. J.

PY - 2025/11/10

Y1 - 2025/11/10

N2 - VS3, a transition metal trichalcogenide that has not been previously reported, was successfully prepared by a high-pressure solid-state synthesis method. Its low-dimensional crystal structure, refined by Rietveld PXRD and confirmed by HR-STEM, features both uncommon V–S coordination polyhedra and S–S dimers. Preliminary characterization reveals low-moment paramagnetic behavior and a semiconducting nature.

AB - VS3, a transition metal trichalcogenide that has not been previously reported, was successfully prepared by a high-pressure solid-state synthesis method. Its low-dimensional crystal structure, refined by Rietveld PXRD and confirmed by HR-STEM, features both uncommon V–S coordination polyhedra and S–S dimers. Preliminary characterization reveals low-moment paramagnetic behavior and a semiconducting nature.

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M3 - Article

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AN - SCOPUS:105021088889

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EP - 22181

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 44

ER -

Low-Dimensional VS₃Synthesized at Elevated Pressure

Abstract

All Science Journal Classification (ASJC) codes

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