Ligand promoted reductive elimination from Zr(IV). The preparation of zirconacycles from alkylzirconium(IV) hydrides and alkynes

Masaaki Yoshifuji; Kerrie I. Gell; Jeffrey Schwartz

doi:10.1016/S0022-328X(00)85047-0

Ligand promoted reductive elimination from Zr(IV). The preparation of zirconacycles from alkylzirconium(IV) hydrides and alkynes

Masaaki Yoshifuji
, Kerrie I. Gell
, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Alkynes induce reductive elimination of alkane from Cp₂Zr(H)(R); zirconacyclopentadienes are formed as well.

Original language	English (US)
Pages (from-to)	C15-C18
Journal	Journal of Organometallic Chemistry
Volume	153
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)85047-0
State	Published - Jun 20 1978

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)85047-0

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title = "Ligand promoted reductive elimination from Zr(IV). The preparation of zirconacycles from alkylzirconium(IV) hydrides and alkynes",

abstract = "Alkynes induce reductive elimination of alkane from Cp2Zr(H)(R); zirconacyclopentadienes are formed as well.",

author = "Masaaki Yoshifuji and Gell, \{Kerrie I.\} and Jeffrey Schwartz",

year = "1978",

month = jun,

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doi = "10.1016/S0022-328X(00)85047-0",

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AU - Yoshifuji, Masaaki

AU - Gell, Kerrie I.

AU - Schwartz, Jeffrey

PY - 1978/6/20

Y1 - 1978/6/20

N2 - Alkynes induce reductive elimination of alkane from Cp2Zr(H)(R); zirconacyclopentadienes are formed as well.

AB - Alkynes induce reductive elimination of alkane from Cp2Zr(H)(R); zirconacyclopentadienes are formed as well.

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U2 - 10.1016/S0022-328X(00)85047-0

DO - 10.1016/S0022-328X(00)85047-0

M3 - Article

AN - SCOPUS:0001827527

SN - 0022-328X

VL - 153

SP - C15-C18

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Ligand promoted reductive elimination from Zr(IV). The preparation of zirconacycles from alkylzirconium(IV) hydrides and alkynes

Abstract

All Science Journal Classification (ASJC) codes

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