Laser direct writing of hydrous ruthenium dioxide micro-pseudocapacitors

Craig B. Arnold; Ryan C. Wartena; Bhanu Pratap; Karen E. Swider-Lyons; Alberto Piqué

Laser direct writing of hydrous ruthenium dioxide micro-pseudocapacitors

Craig B. Arnold, Ryan C. Wartena, Bhanu Pratap, Karen E. Swider-Lyons, Alberto Piqué

Research output: Contribution to journal › Conference article › peer-review

Abstract

We are using a laser engineering approach to develop and optimize hydrous ruthenium dioxide (RuO_xH_y or RuO₂·0.5 H₂O) pseudocapacitors. We employ a novel laser forward transfer process, Matrix Assisted Pulsed Laser Evaporation Direct Write (MAPLE-DW), in combination with UV laser machining, to fabricate mesoscale pseudocapacitors and microbatteries under ambient temperature and atmospheric conditions. Thin films with the desired high surface area morphology are obtained without compromising their electrochemical performance. The highest capacitance structures are achieved by depositing mixtures of sulfuric acid with the RuO₂·0.5 H₂O electrode material. Our pseudocapacitors exhibit linear discharge behavior and their properties scale proportionately when assembled in parallel and series configurations.

Original language	English (US)
Pages (from-to)	275-280
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	698
State	Published - 2002
Externally published	Yes
Event	Electronactive Polymers and Rapid Prototyping - Boston, MA, United States Duration: Nov 26 2001 → Nov 30 2001

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Cite this

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title = "Laser direct writing of hydrous ruthenium dioxide micro-pseudocapacitors",

abstract = "We are using a laser engineering approach to develop and optimize hydrous ruthenium dioxide (RuOxHy or RuO2·0.5 H2O) pseudocapacitors. We employ a novel laser forward transfer process, Matrix Assisted Pulsed Laser Evaporation Direct Write (MAPLE-DW), in combination with UV laser machining, to fabricate mesoscale pseudocapacitors and microbatteries under ambient temperature and atmospheric conditions. Thin films with the desired high surface area morphology are obtained without compromising their electrochemical performance. The highest capacitance structures are achieved by depositing mixtures of sulfuric acid with the RuO2·0.5 H2O electrode material. Our pseudocapacitors exhibit linear discharge behavior and their properties scale proportionately when assembled in parallel and series configurations.",

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volume = "698",

pages = "275--280",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

note = "Electronactive Polymers and Rapid Prototyping ; Conference date: 26-11-2001 Through 30-11-2001",

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TY - JOUR

T1 - Laser direct writing of hydrous ruthenium dioxide micro-pseudocapacitors

AU - Arnold, Craig B.

AU - Wartena, Ryan C.

AU - Pratap, Bhanu

AU - Swider-Lyons, Karen E.

AU - Piqué, Alberto

PY - 2002

Y1 - 2002

N2 - We are using a laser engineering approach to develop and optimize hydrous ruthenium dioxide (RuOxHy or RuO2·0.5 H2O) pseudocapacitors. We employ a novel laser forward transfer process, Matrix Assisted Pulsed Laser Evaporation Direct Write (MAPLE-DW), in combination with UV laser machining, to fabricate mesoscale pseudocapacitors and microbatteries under ambient temperature and atmospheric conditions. Thin films with the desired high surface area morphology are obtained without compromising their electrochemical performance. The highest capacitance structures are achieved by depositing mixtures of sulfuric acid with the RuO2·0.5 H2O electrode material. Our pseudocapacitors exhibit linear discharge behavior and their properties scale proportionately when assembled in parallel and series configurations.

AB - We are using a laser engineering approach to develop and optimize hydrous ruthenium dioxide (RuOxHy or RuO2·0.5 H2O) pseudocapacitors. We employ a novel laser forward transfer process, Matrix Assisted Pulsed Laser Evaporation Direct Write (MAPLE-DW), in combination with UV laser machining, to fabricate mesoscale pseudocapacitors and microbatteries under ambient temperature and atmospheric conditions. Thin films with the desired high surface area morphology are obtained without compromising their electrochemical performance. The highest capacitance structures are achieved by depositing mixtures of sulfuric acid with the RuO2·0.5 H2O electrode material. Our pseudocapacitors exhibit linear discharge behavior and their properties scale proportionately when assembled in parallel and series configurations.

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M3 - Conference article

AN - SCOPUS:0036353710

SN - 0272-9172

VL - 698

SP - 275

EP - 280

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

T2 - Electronactive Polymers and Rapid Prototyping

Y2 - 26 November 2001 through 30 November 2001

ER -

Laser direct writing of hydrous ruthenium dioxide micro-pseudocapacitors

Abstract

All Science Journal Classification (ASJC) codes

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