Laminar flame speeds of C5 to C8 n-alkanes at elevated pressures: Experimental determination, fuel similarity, and stretch sensitivity

A. P. Kelley, A. J. Smallbone, D. L. Zhu, C. K. Law

Research output: Contribution to journalArticle

107 Scopus citations

Abstract

Experimental data of high fidelity on the laminar flame speeds and Markstein lengths of C5-C8 n-alkane mixtures with air at elevated pressures were determined from the propagation velocities of spark-ignited, expanding flames in a newly-designed heated, high-and constant-pressure chamber, using nonlinear extrapolation. Results show that the laminar flame speeds of these fuels are basically similar, hence extending previous observations of the fuel similarity to the high-pressure range of 10-20 atm. A companion analysis of the computed flame structure reveals comparable similarity for the thermal properties as well as the key intermediates and reactions, thereby supporting the observed global flame speed similarity. The study further shows that the influence of stretch diminishes with increasing pressure because of the concomitant reduction of the flame thickness, implying not only reduced error in the determination of laminar flame speeds from stretched flames at elevated pressures, but also substantial simplification in the modeling of turbulent flames because of the diminished importance of stretch.

Original languageEnglish (US)
Pages (from-to)963-970
Number of pages8
JournalProceedings of the Combustion Institute
Volume33
Issue number1
DOIs
StatePublished - Jan 10 2011

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Mechanical Engineering
  • Physical and Theoretical Chemistry

Keywords

  • Flame speed
  • Nonlinear extrapolation
  • Outwardly propagating flame
  • n-Alkane

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