Iron(IV) porphyrins from iron(III) porphyrin cation radicals

John T. Groves; Robert Quinn; Thomas J. McMurry; George Lang; Brian Boso

doi:10.1039/C39840001455

Iron(IV) porphyrins from iron(III) porphyrin cation radicals

John T. Groves, Robert Quinn, Thomas J. McMurry, George Lang, Brian Boso

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The preparation and spectroscopic data of FeTMP(ClO₄)₂ [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant d_x2−y2 iron orbital (¹H n.m.r.) and (b) in the iron(iv) state (Mössbauer spectroscopy).

Original language	English (US)
Pages (from-to)	1455-1456
Number of pages	2
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39840001455
State	Published - Jan 1 1984
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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title = "Iron(IV) porphyrins from iron(III) porphyrin cation radicals",

abstract = "The preparation and spectroscopic data of FeTMP(ClO4)2 [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2−y2 iron orbital (1H n.m.r.) and (b) in the iron(iv) state (M{\"o}ssbauer spectroscopy).",

author = "Groves, {John T.} and Robert Quinn and McMurry, {Thomas J.} and George Lang and Brian Boso",

year = "1984",

month = jan,

day = "1",

doi = "10.1039/C39840001455",

language = "English (US)",

pages = "1455--1456",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "21",

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TY - JOUR

T1 - Iron(IV) porphyrins from iron(III) porphyrin cation radicals

AU - Groves, John T.

AU - Quinn, Robert

AU - McMurry, Thomas J.

AU - Lang, George

AU - Boso, Brian

PY - 1984/1/1

Y1 - 1984/1/1

N2 - The preparation and spectroscopic data of FeTMP(ClO4)2 [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2−y2 iron orbital (1H n.m.r.) and (b) in the iron(iv) state (Mössbauer spectroscopy).

AB - The preparation and spectroscopic data of FeTMP(ClO4)2 [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2−y2 iron orbital (1H n.m.r.) and (b) in the iron(iv) state (Mössbauer spectroscopy).

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U2 - 10.1039/C39840001455

DO - 10.1039/C39840001455

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SP - 1455

EP - 1456

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Iron(IV) porphyrins from iron(III) porphyrin cation radicals

Abstract

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