TY - JOUR
T1 - Iron(IV) porphyrins from iron(III) porphyrin cation radicals
AU - Groves, John T.
AU - Quinn, Robert
AU - McMurry, Thomas J.
AU - Lang, George
AU - Boso, Brian
PY - 1984
Y1 - 1984
N2 - The preparation and spectroscopic data of FeTMP(ClO4)2 [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2−y2 iron orbital (1H n.m.r.) and (b) in the iron(iv) state (Mössbauer spectroscopy).
AB - The preparation and spectroscopic data of FeTMP(ClO4)2 [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2−y2 iron orbital (1H n.m.r.) and (b) in the iron(iv) state (Mössbauer spectroscopy).
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U2 - 10.1039/C39840001455
DO - 10.1039/C39840001455
M3 - Article
AN - SCOPUS:37049096256
SN - 0022-4936
SP - 1455
EP - 1456
JO - Journal of the Chemical Society - Series Chemical Communications
JF - Journal of the Chemical Society - Series Chemical Communications
IS - 21
ER -