The preparation and spectroscopic data of FeTMP(ClO4)2 [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2−y2 iron orbital (1H n.m.r.) and (b) in the iron(iv) state (Mössbauer spectroscopy).
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society - Series Chemical Communications|
|State||Published - Jan 1 1984|
All Science Journal Classification (ASJC) codes
- Molecular Medicine