Iron(IV) porphyrins from iron(III) porphyrin cation radicals

John T. Groves, Robert Quinn, Thomas J. McMurry, George Lang, Brian Boso

Research output: Contribution to journalArticlepeer-review

37 Scopus citations


The preparation and spectroscopic data of FeTMP(ClO4)2 [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2−y2 iron orbital (1H n.m.r.) and (b) in the iron(iv) state (Mössbauer spectroscopy).

Original languageEnglish (US)
Pages (from-to)1455-1456
Number of pages2
JournalJournal of the Chemical Society - Series Chemical Communications
Issue number21
StatePublished - 1984
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Molecular Medicine


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