Abstract
The preparation and spectroscopic data of FeTMP(ClO4)2 [(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe-MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2−y2 iron orbital (1H n.m.r.) and (b) in the iron(iv) state (Mössbauer spectroscopy).
Original language | English (US) |
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Pages (from-to) | 1455-1456 |
Number of pages | 2 |
Journal | Journal of the Chemical Society - Series Chemical Communications |
Issue number | 21 |
DOIs | |
State | Published - Jan 1 1984 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Molecular Medicine