Interdigitated conducting tetrathiafulvalene-based coordination networks

Damien Bechu; Lilia S. Xie; Nolwenn Le Breton; Sylvie Choua; Mircea Dincǎ; Mir Wais Hosseini; Stéphane A. Baudron

doi:10.1039/c9cc09960c

Interdigitated conducting tetrathiafulvalene-based coordination networks

Damien Bechu, Lilia S. Xie, Nolwenn Le Breton, Sylvie Choua, Mircea Dincǎ, Mir Wais Hosseini, Stéphane A. Baudron

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)₂ nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10^-6vs. 10^-12 S cm^-1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals.

Original language	English (US)
Pages (from-to)	2407-2410
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	16
DOIs	https://doi.org/10.1039/c9cc09960c
State	Published - Feb 25 2020
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c9cc09960c

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title = "Interdigitated conducting tetrathiafulvalene-based coordination networks",

abstract = "Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10-6vs. 10-12 S cm-1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals.",

author = "Damien Bechu and Xie, {Lilia S.} and {Le Breton}, Nolwenn and Sylvie Choua and Mircea Dincǎ and Hosseini, {Mir Wais} and Baudron, {St{\'e}phane A.}",

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T1 - Interdigitated conducting tetrathiafulvalene-based coordination networks

AU - Bechu, Damien

AU - Xie, Lilia S.

AU - Le Breton, Nolwenn

AU - Choua, Sylvie

AU - Dincǎ, Mircea

AU - Hosseini, Mir Wais

AU - Baudron, Stéphane A.

PY - 2020/2/25

Y1 - 2020/2/25

N2 - Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10-6vs. 10-12 S cm-1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals.

AB - Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10-6vs. 10-12 S cm-1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals.

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DO - 10.1039/c9cc09960c

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SP - 2407

EP - 2410

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Interdigitated conducting tetrathiafulvalene-based coordination networks

Abstract

All Science Journal Classification (ASJC) codes

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