Interception of Bis(η3-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

Alan Gollaszewski; Jeffrey Schwartz

doi:10.1021/om00121a047

Interception of Bis(η³-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

Alan Gollaszewski
, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.

Original language	English (US)
Pages (from-to)	417-419
Number of pages	3
Journal	Organometallics
Volume	4
Issue number	2
DOIs	https://doi.org/10.1021/om00121a047
State	Published - Feb 1985

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om00121a047

Cite this

@article{5e48e24d453c43af8c265551558e59f4,

title = "Interception of Bis(η3-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents",

abstract = "Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.",

author = "Alan Gollaszewski and Jeffrey Schwartz",

year = "1985",

month = feb,

doi = "10.1021/om00121a047",

language = "English (US)",

volume = "4",

pages = "417--419",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Interception of Bis(η3-allylic)palladium Intermediates by Maleic Anhydride

T2 - A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

AU - Gollaszewski, Alan

AU - Schwartz, Jeffrey

PY - 1985/2

Y1 - 1985/2

N2 - Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.

AB - Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.

UR - https://www.scopus.com/pages/publications/0000333864

UR - https://www.scopus.com/pages/publications/0000333864#tab=citedBy

U2 - 10.1021/om00121a047

DO - 10.1021/om00121a047

M3 - Article

AN - SCOPUS:0000333864

SN - 0276-7333

VL - 4

SP - 417

EP - 419

JO - Organometallics

JF - Organometallics

IS - 2

ER -

Interception of Bis(η³-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this