Interception of Bis(η3-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

Alan Gollaszewski, Jeffrey Schwartz

Research output: Contribution to journalArticle

58 Scopus citations

Abstract

Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.

Original languageEnglish (US)
Pages (from-to)417-419
Number of pages3
JournalOrganometallics
Volume4
Issue number2
DOIs
StatePublished - Feb 1985

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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