Interception of Bis(η3-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

Alan Gollaszewski; Jeffrey Schwartz

doi:10.1021/om00121a047

Interception of Bis(η³-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

Alan Gollaszewski, Jeffrey Schwartz

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Abstract

Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.

Original language	English (US)
Pages (from-to)	417-419
Number of pages	3
Journal	Organometallics
Volume	4
Issue number	2
DOIs	https://doi.org/10.1021/om00121a047
State	Published - Feb 1985

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00121a047

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title = "Interception of Bis(η3-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents",

abstract = "Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.",

author = "Alan Gollaszewski and Jeffrey Schwartz",

year = "1985",

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doi = "10.1021/om00121a047",

language = "English (US)",

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T1 - Interception of Bis(η3-allylic)palladium Intermediates by Maleic Anhydride

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AU - Schwartz, Jeffrey

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Y1 - 1985/2

N2 - Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.

AB - Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.

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Interception of Bis(η³-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

Abstract

All Science Journal Classification (ASJC) codes

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