Interception of Bis(η3-allylic)palladium Intermediates by Maleic Anhydride: A Change in an Overall Carbon-Carbon Bond Forming Scheme Using Organotin Reagents

Alan Gollaszewski, Jeffrey Schwartz

Research output: Contribution to journalArticlepeer-review

58 Scopus citations

Abstract

Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.

Original languageEnglish (US)
Pages (from-to)417-419
Number of pages3
JournalOrganometallics
Volume4
Issue number2
DOIs
StatePublished - Feb 1985

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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