Allylic tin species react with allylic palladium chlorides to yield bis(allylic)palladium complexes. In the absence of maleic anhydride no coupling by reductive elimination is noted; in its presence, high yields of 1,5-dienes can be realized. Palladium-catalyzed coupling of allylic tin reagents with allylic chlorides is described.
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry