Insulator to correlated metal transition in V1-x Mox O2

K. L. Holman; T. M. McQueen; A. J. Williams; T. Klimczuk; P. W. Stephens; H. W. Zandbergen; Q. Xu; F. Ronning; R. J. Cava

doi:10.1103/PhysRevB.79.245114

Insulator to correlated metal transition in V1-x Mox O2

K. L. Holman, T. M. McQueen, A. J. Williams, T. Klimczuk, P. W. Stephens, H. W. Zandbergen, Q. Xu, F. Ronning, R. J. Cava

Research output: Contribution to journal › Article › peer-review

86 Scopus citations

Abstract

Although many materials display the transition from insulating to metallic behavior on doping, only a few, such as VO2, have the right combination of crystal structure and physical properties to serve as model systems. Here we report the electronic and structural characteristics of the insulator to metal transition in V1-x Mox O2, which we have studied over the range 0.0≤x≤0.50 through characterization of the electrical resistivity, magnetic susceptibility, specific heat, and average- and short-range crystal structures. We find that metal-metal pairing exists in small domains in the doped metallic phases and an unexpected phenomenology for the crossover between a Curie-Weiss insulating regime and an intermediate mass metallic regime. An electronic phase diagram is presented.

Original language	English (US)
Article number	245114
Journal	Physical Review B - Condensed Matter and Materials Physics
Volume	79
Issue number	24
DOIs	https://doi.org/10.1103/PhysRevB.79.245114
State	Published - Jun 15 2009

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

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10.1103/PhysRevB.79.245114

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title = "Insulator to correlated metal transition in V1-x Mox O2",

abstract = "Although many materials display the transition from insulating to metallic behavior on doping, only a few, such as VO2, have the right combination of crystal structure and physical properties to serve as model systems. Here we report the electronic and structural characteristics of the insulator to metal transition in V1-x Mox O2, which we have studied over the range 0.0≤x≤0.50 through characterization of the electrical resistivity, magnetic susceptibility, specific heat, and average- and short-range crystal structures. We find that metal-metal pairing exists in small domains in the doped metallic phases and an unexpected phenomenology for the crossover between a Curie-Weiss insulating regime and an intermediate mass metallic regime. An electronic phase diagram is presented.",

author = "Holman, {K. L.} and McQueen, {T. M.} and Williams, {A. J.} and T. Klimczuk and Stephens, {P. W.} and Zandbergen, {H. W.} and Q. Xu and F. Ronning and Cava, {R. J.}",

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AU - Holman, K. L.

AU - McQueen, T. M.

AU - Williams, A. J.

AU - Klimczuk, T.

AU - Stephens, P. W.

AU - Zandbergen, H. W.

AU - Xu, Q.

AU - Ronning, F.

AU - Cava, R. J.

PY - 2009/6/15

Y1 - 2009/6/15

N2 - Although many materials display the transition from insulating to metallic behavior on doping, only a few, such as VO2, have the right combination of crystal structure and physical properties to serve as model systems. Here we report the electronic and structural characteristics of the insulator to metal transition in V1-x Mox O2, which we have studied over the range 0.0≤x≤0.50 through characterization of the electrical resistivity, magnetic susceptibility, specific heat, and average- and short-range crystal structures. We find that metal-metal pairing exists in small domains in the doped metallic phases and an unexpected phenomenology for the crossover between a Curie-Weiss insulating regime and an intermediate mass metallic regime. An electronic phase diagram is presented.

AB - Although many materials display the transition from insulating to metallic behavior on doping, only a few, such as VO2, have the right combination of crystal structure and physical properties to serve as model systems. Here we report the electronic and structural characteristics of the insulator to metal transition in V1-x Mox O2, which we have studied over the range 0.0≤x≤0.50 through characterization of the electrical resistivity, magnetic susceptibility, specific heat, and average- and short-range crystal structures. We find that metal-metal pairing exists in small domains in the doped metallic phases and an unexpected phenomenology for the crossover between a Curie-Weiss insulating regime and an intermediate mass metallic regime. An electronic phase diagram is presented.

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Insulator to correlated metal transition in V1-x Mox O2

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