TY - JOUR
T1 - Influence of alkyne spacers on the performance of thiophene-based donors in bulk-heterojunction organic photovoltaic cells
AU - Marques dos Santos, John
AU - Neophytou, Marios
AU - Wiles, Alan
AU - Howells, Calvyn Travis
AU - Ashraf, Raja Shahid
AU - McCulloch, Iain
AU - Cooke, Graeme
N1 - Publisher Copyright:
© 2021
PY - 2021/4
Y1 - 2021/4
N2 - The ever-increasing demand for renewable energy has led to the intensification of research focused upon harnessing the abundant energy from sunlight. Solution processed organic solar cells fabricated using conjugated polymer donor materials dominated the early development of organic photovoltaics (OPV). More recently, organic solar cells fabricated using small molecule donors have become increasingly attractive due to the advantages these systems have over their polymeric counterparts. These include reproducible synthesis and the ability to more accurately develop structure-activity relationships. Here, we report the synthesis of thiophene based small molecule donors that have been used to investigate the influence of alkyne π-spacers on the optical, electronic and photovoltaic properties of solution-processable bulk-heterojunction (BHJ) organic OPV cells. Additionally, we compare the addition of 3,4-ethylenedioxythiophene (EDOT) units in place of the end-thiophene of these derivatives. We found that the compounds featuring alkyne moieties displayed poor charge transfer and blue-shifted UV–vis spectra, whereas the incorporation of the EDOT units increased charge transfer for the non-alkyne derivative resulting in red-shifted absorbance. DFT calculations predicted higher charge separation/mobility and lower charge generation for the compounds without alkyne units. Indeed, greater Jsc values and higher PCEs were found for the compounds lacking alkyne spacers. EDOT containing compounds showed poor performance which is likely due to an unfavourable morphology and higher HOMO level, leading to lower Voc. Hence, the simplest 5T-1 molecule showed the highest performance of 3.24%, which is c.a. 1.6x that of the alkyne-containing 5TA-1 and c.a. 2.9x that of the EDOT-containing derivative. This study demonstrates that alkyne spacers can be detrimental to orbital interactions, charge transfer and OPV performance, and that the EDOT unit can be added to provide greater charge transfer due to its auxiliary donating ability. However, careful design is required to ensure higher Voc values and a favourable morphology in thiophene-based solution-processable OPVs.
AB - The ever-increasing demand for renewable energy has led to the intensification of research focused upon harnessing the abundant energy from sunlight. Solution processed organic solar cells fabricated using conjugated polymer donor materials dominated the early development of organic photovoltaics (OPV). More recently, organic solar cells fabricated using small molecule donors have become increasingly attractive due to the advantages these systems have over their polymeric counterparts. These include reproducible synthesis and the ability to more accurately develop structure-activity relationships. Here, we report the synthesis of thiophene based small molecule donors that have been used to investigate the influence of alkyne π-spacers on the optical, electronic and photovoltaic properties of solution-processable bulk-heterojunction (BHJ) organic OPV cells. Additionally, we compare the addition of 3,4-ethylenedioxythiophene (EDOT) units in place of the end-thiophene of these derivatives. We found that the compounds featuring alkyne moieties displayed poor charge transfer and blue-shifted UV–vis spectra, whereas the incorporation of the EDOT units increased charge transfer for the non-alkyne derivative resulting in red-shifted absorbance. DFT calculations predicted higher charge separation/mobility and lower charge generation for the compounds without alkyne units. Indeed, greater Jsc values and higher PCEs were found for the compounds lacking alkyne spacers. EDOT containing compounds showed poor performance which is likely due to an unfavourable morphology and higher HOMO level, leading to lower Voc. Hence, the simplest 5T-1 molecule showed the highest performance of 3.24%, which is c.a. 1.6x that of the alkyne-containing 5TA-1 and c.a. 2.9x that of the EDOT-containing derivative. This study demonstrates that alkyne spacers can be detrimental to orbital interactions, charge transfer and OPV performance, and that the EDOT unit can be added to provide greater charge transfer due to its auxiliary donating ability. However, careful design is required to ensure higher Voc values and a favourable morphology in thiophene-based solution-processable OPVs.
KW - Alkyne
KW - DFT
KW - EDOT
KW - Organic photovoltaics
KW - Power conversion efficiency
KW - Thiophene
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U2 - 10.1016/j.dyepig.2021.109152
DO - 10.1016/j.dyepig.2021.109152
M3 - Article
AN - SCOPUS:85100419499
SN - 0143-7208
VL - 188
JO - Dyes and Pigments
JF - Dyes and Pigments
M1 - 109152
ER -