Improved field-effect transistor performance of a benzotrithiophene polymer through ketal cleavage in the solid state

Christian B. Nielsen; Eun Ho Sohn; Dong Jun Cho; Bob C. Schroeder; Jeremy Smith; Mongryong Lee; Thomas D. Anthopoulos; Kigook Song; Iain McCulloch

doi:10.1021/am303138q

Improved field-effect transistor performance of a benzotrithiophene polymer through ketal cleavage in the solid state

Christian B. Nielsen, Eun Ho Sohn, Dong Jun Cho, Bob C. Schroeder, Jeremy Smith, Mongryong Lee, Thomas D. Anthopoulos, Kigook Song, Iain McCulloch

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A benzotrithiophene polymer with a new thermally cleavable ketal substituent is reported. It is shown how this functional group can be used to facilitate solvent processing and, subsequently, how it can be removed by a thermal annealing process to generate a structurally ordered and crystalline thin film with significantly improved field-effect transistor properties.

Original language	English (US)
Pages (from-to)	1806-1810
Number of pages	5
Journal	ACS Applied Materials and Interfaces
Volume	5
Issue number	5
DOIs	https://doi.org/10.1021/am303138q
State	Published - Mar 13 2013
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Materials Science

Keywords

benzotrithiophene
conjugated polymers
field-effect transistors
hole mobility
thermal cleavage

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10.1021/am303138q

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abstract = "A benzotrithiophene polymer with a new thermally cleavable ketal substituent is reported. It is shown how this functional group can be used to facilitate solvent processing and, subsequently, how it can be removed by a thermal annealing process to generate a structurally ordered and crystalline thin film with significantly improved field-effect transistor properties.",

keywords = "benzotrithiophene, conjugated polymers, field-effect transistors, hole mobility, thermal cleavage",

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AU - Nielsen, Christian B.

AU - Sohn, Eun Ho

AU - Cho, Dong Jun

AU - Schroeder, Bob C.

AU - Smith, Jeremy

AU - Lee, Mongryong

AU - Anthopoulos, Thomas D.

AU - Song, Kigook

AU - McCulloch, Iain

PY - 2013/3/13

Y1 - 2013/3/13

N2 - A benzotrithiophene polymer with a new thermally cleavable ketal substituent is reported. It is shown how this functional group can be used to facilitate solvent processing and, subsequently, how it can be removed by a thermal annealing process to generate a structurally ordered and crystalline thin film with significantly improved field-effect transistor properties.

AB - A benzotrithiophene polymer with a new thermally cleavable ketal substituent is reported. It is shown how this functional group can be used to facilitate solvent processing and, subsequently, how it can be removed by a thermal annealing process to generate a structurally ordered and crystalline thin film with significantly improved field-effect transistor properties.

KW - benzotrithiophene

KW - conjugated polymers

KW - field-effect transistors

KW - hole mobility

KW - thermal cleavage

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ER -

Improved field-effect transistor performance of a benzotrithiophene polymer through ketal cleavage in the solid state

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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