TY - JOUR
T1 - Importance of Specific Heat Characterization when Reporting New Superconductors
T2 - An Example of Superconductivity in LiGa 2 Rh
AU - Carnicom, Elizabeth M.
AU - Xie, Weiwei
AU - Yang, Zoe
AU - Górnicka, Karolina
AU - Kong, Tai
AU - Klimczuk, Tomasz
AU - Cava, Robert J.
N1 - Publisher Copyright:
© Copyright 2019 American Chemical Society.
PY - 2019/3/26
Y1 - 2019/3/26
N2 - We show that the full-Heusler compound LiGa 2 Rh is a superconductor with T c = 2.4 K. The new superconductor was found as a result of an intuition-based extension of a database search for superconductors that looked for the presence of peaks in the electronic band structure near the Fermi energy. The measurement of the entropy loss during the transition from the nonsuperconducting to the superconducting state, a straightforward measurement rarely presented in reports of "new" superconducting materials, played a critical role in identifying and isolating the superconducting compound. This study presents a particularly good example of how specific heat measurements are important for the identification and isolation of a new superconductor, since much more frequently reported resistive and magnetic susceptibility characterizations are often not enough to confirm the identification of a new superconducting material.
AB - We show that the full-Heusler compound LiGa 2 Rh is a superconductor with T c = 2.4 K. The new superconductor was found as a result of an intuition-based extension of a database search for superconductors that looked for the presence of peaks in the electronic band structure near the Fermi energy. The measurement of the entropy loss during the transition from the nonsuperconducting to the superconducting state, a straightforward measurement rarely presented in reports of "new" superconducting materials, played a critical role in identifying and isolating the superconducting compound. This study presents a particularly good example of how specific heat measurements are important for the identification and isolation of a new superconductor, since much more frequently reported resistive and magnetic susceptibility characterizations are often not enough to confirm the identification of a new superconducting material.
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U2 - 10.1021/acs.chemmater.9b00258
DO - 10.1021/acs.chemmater.9b00258
M3 - Article
AN - SCOPUS:85063146658
SN - 0897-4756
VL - 31
SP - 2164
EP - 2173
JO - Chemistry of Materials
JF - Chemistry of Materials
IS - 6
ER -