Hydrozirconation: A New Transition Metal Reagent for Organic Synthesis

Jeffrey Schwartz; Jay A. Labinger

doi:10.1002/anie.197603331

Hydrozirconation: A New Transition Metal Reagent for Organic Synthesis

Jeffrey Schwartz, Jay A. Labinger

Research output: Contribution to journal › Article › peer-review

571 Scopus citations

Abstract

Hydrozirconation has recently been developed as a procedure for functionalizing alkenes, alkynes, and 1,3‐dienes via organozirconium(IV) intermediates. These intermediates react with a variety of electrophilic reagents to give organic products in high yield. Mechanisms of reactions involved in these sequences are discussed.

Original language	English (US)
Pages (from-to)	333-340
Number of pages	8
Journal	Angewandte Chemie International Edition in English
Volume	15
Issue number	6
DOIs	https://doi.org/10.1002/anie.197603331
State	Published - Jun 1976

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

Hydrozirconation
Synthetic methods
Zirconium

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10.1002/anie.197603331

Cite this

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title = "Hydrozirconation: A New Transition Metal Reagent for Organic Synthesis",

abstract = "Hydrozirconation has recently been developed as a procedure for functionalizing alkenes, alkynes, and 1,3‐dienes via organozirconium(IV) intermediates. These intermediates react with a variety of electrophilic reagents to give organic products in high yield. Mechanisms of reactions involved in these sequences are discussed.",

keywords = "Hydrozirconation, Synthetic methods, Zirconium",

author = "Jeffrey Schwartz and Labinger, \{Jay A.\}",

year = "1976",

month = jun,

doi = "10.1002/anie.197603331",

language = "English (US)",

volume = "15",

pages = "333--340",

journal = "Angewandte Chemie International Edition in English",

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AU - Schwartz, Jeffrey

AU - Labinger, Jay A.

PY - 1976/6

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N2 - Hydrozirconation has recently been developed as a procedure for functionalizing alkenes, alkynes, and 1,3‐dienes via organozirconium(IV) intermediates. These intermediates react with a variety of electrophilic reagents to give organic products in high yield. Mechanisms of reactions involved in these sequences are discussed.

AB - Hydrozirconation has recently been developed as a procedure for functionalizing alkenes, alkynes, and 1,3‐dienes via organozirconium(IV) intermediates. These intermediates react with a variety of electrophilic reagents to give organic products in high yield. Mechanisms of reactions involved in these sequences are discussed.

KW - Hydrozirconation

KW - Synthetic methods

KW - Zirconium

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U2 - 10.1002/anie.197603331

DO - 10.1002/anie.197603331

M3 - Article

AN - SCOPUS:84982433710

SN - 0570-0833

VL - 15

SP - 333

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 6

ER -

Hydrozirconation: A New Transition Metal Reagent for Organic Synthesis

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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