TY - GEN
T1 - Hydrogen storage in microporous coordination solids with exposed metal sites
AU - Dinca, Mircea
AU - Kaye, Steven S.
AU - Yu, Anta F.
AU - Long, Jeffrey R.
PY - 2006
Y1 - 2006
N2 - Methods for synthesizing frameworks bearing coordinatively-unsaturated metal centers are being developed in order to increase the H2 binding enthalpy within microporous coordination solids. The porosity and hydrogen storage properties of the dehydrated Prussian blue analogues Ga[Co(CN)6], Fe4[Fe(CN)6]3, M3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn), M2[Fe(CN)6] (M = Mn, Co, Ni, Cu), and Co3[Co(CN)5]2 have been investigated. Means of incorporating metal carbonyl units within Zn4O(1,4-benzenedicarboxylate)3 have been devised, and attempts at decarbonylating the resulting materials will be described. In addition, the use of pyrazole- and tetrazole-based ligands for generating frameworks with open metal coordination sites will be discussed, with emphasis on a new sodalite-type framework exhibiting a high volumetric H2 storage capacity.
AB - Methods for synthesizing frameworks bearing coordinatively-unsaturated metal centers are being developed in order to increase the H2 binding enthalpy within microporous coordination solids. The porosity and hydrogen storage properties of the dehydrated Prussian blue analogues Ga[Co(CN)6], Fe4[Fe(CN)6]3, M3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn), M2[Fe(CN)6] (M = Mn, Co, Ni, Cu), and Co3[Co(CN)5]2 have been investigated. Means of incorporating metal carbonyl units within Zn4O(1,4-benzenedicarboxylate)3 have been devised, and attempts at decarbonylating the resulting materials will be described. In addition, the use of pyrazole- and tetrazole-based ligands for generating frameworks with open metal coordination sites will be discussed, with emphasis on a new sodalite-type framework exhibiting a high volumetric H2 storage capacity.
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M3 - Conference contribution
AN - SCOPUS:34047255930
SN - 0841274266
SN - 9780841274266
T3 - ACS National Meeting Book of Abstracts
BT - Abstracts of Papers - 232nd American Chemical Society Meeting and Exposition
T2 - 232nd American Chemical Society Meeting and Exposition
Y2 - 10 September 2006 through 14 September 2006
ER -