Hydrogen abstraction on photolysis of a naphthocarborane

Alexander Z. Bradley; A. James Link; Kaustav Biswas; Daniel Kahne; Jeffrey Schwartz; Maitland Jones; Zhendong Zhu; Matthew S. Platz

doi:10.1016/S0040-4039(00)01578-1

Hydrogen abstraction on photolysis of a naphthocarborane

Alexander Z. Bradley, A. James Link, Kaustav Biswas, Daniel Kahne, Jeffrey Schwartz, Maitland Jones, Zhendong Zhu, Matthew S. Platz

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Photolysis of 'naphtho-o-carborane' in the presence of excellent hydrogen donors such as 1,4-cyclohexadiene leads to quantitative double hydrogen abstraction. Other molecules, including supercoiled DNA, similarly act as hydrogen atom donors towards photolyzed naphtho-o-carborane. A diradical intermediate is proposed. (C) 2000 Elsevier Science Ltd.

Original language	English (US)
Pages (from-to)	8691-8694
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	45
DOIs	https://doi.org/10.1016/S0040-4039(00)01578-1
State	Published - Nov 4 2000

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Hydrogen abstraction on photolysis of a naphthocarborane",

abstract = "Photolysis of 'naphtho-o-carborane' in the presence of excellent hydrogen donors such as 1,4-cyclohexadiene leads to quantitative double hydrogen abstraction. Other molecules, including supercoiled DNA, similarly act as hydrogen atom donors towards photolyzed naphtho-o-carborane. A diradical intermediate is proposed. (C) 2000 Elsevier Science Ltd.",

author = "Bradley, {Alexander Z.} and Link, {A. James} and Kaustav Biswas and Daniel Kahne and Jeffrey Schwartz and Maitland Jones and Zhendong Zhu and Platz, {Matthew S.}",

note = "Funding Information: This work was supported by the National Science Foundation through grant CHE-97-02823. AZB thanks the Council on Science and Technology of Princeton University and the Camille and Henry Dreyfus Foundation Special Grants Program for financial support. ",

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T1 - Hydrogen abstraction on photolysis of a naphthocarborane

AU - Bradley, Alexander Z.

AU - Link, A. James

AU - Biswas, Kaustav

AU - Kahne, Daniel

AU - Schwartz, Jeffrey

AU - Jones, Maitland

AU - Zhu, Zhendong

AU - Platz, Matthew S.

N1 - Funding Information: This work was supported by the National Science Foundation through grant CHE-97-02823. AZB thanks the Council on Science and Technology of Princeton University and the Camille and Henry Dreyfus Foundation Special Grants Program for financial support.

PY - 2000/11/4

Y1 - 2000/11/4

N2 - Photolysis of 'naphtho-o-carborane' in the presence of excellent hydrogen donors such as 1,4-cyclohexadiene leads to quantitative double hydrogen abstraction. Other molecules, including supercoiled DNA, similarly act as hydrogen atom donors towards photolyzed naphtho-o-carborane. A diradical intermediate is proposed. (C) 2000 Elsevier Science Ltd.

AB - Photolysis of 'naphtho-o-carborane' in the presence of excellent hydrogen donors such as 1,4-cyclohexadiene leads to quantitative double hydrogen abstraction. Other molecules, including supercoiled DNA, similarly act as hydrogen atom donors towards photolyzed naphtho-o-carborane. A diradical intermediate is proposed. (C) 2000 Elsevier Science Ltd.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

Hydrogen abstraction on photolysis of a naphthocarborane

Abstract

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