Hydrogen abstraction on photolysis of a naphthocarborane

Alexander Z. Bradley, A. James Link, Kaustav Biswas, Daniel Kahne, Jeffrey Schwartz, Maitland Jones, Zhendong Zhu, Matthew S. Platz

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

Photolysis of 'naphtho-o-carborane' in the presence of excellent hydrogen donors such as 1,4-cyclohexadiene leads to quantitative double hydrogen abstraction. Other molecules, including supercoiled DNA, similarly act as hydrogen atom donors towards photolyzed naphtho-o-carborane. A diradical intermediate is proposed. (C) 2000 Elsevier Science Ltd.

Original languageEnglish (US)
Pages (from-to)8691-8694
Number of pages4
JournalTetrahedron Letters
Volume41
Issue number45
DOIs
StatePublished - Nov 4 2000

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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  • Cite this

    Bradley, A. Z., Link, A. J., Biswas, K., Kahne, D., Schwartz, J., Jones, M., Zhu, Z., & Platz, M. S. (2000). Hydrogen abstraction on photolysis of a naphthocarborane. Tetrahedron Letters, 41(45), 8691-8694. https://doi.org/10.1016/S0040-4039(00)01578-1