Hybrid perovskite light emitting diodes under intense electrical excitation

Hoyeon Kim, Lianfeng Zhao, Jared S. Price, Alex J. Grede, Kwangdong Roh, Alyssa N. Brigeman, Mike Lopez, Barry P. Rand, Noel C. Giebink

Research output: Contribution to journalArticle

39 Scopus citations

Abstract

Hybrid perovskite semiconductors represent a promising platform for color-tunable light emitting diodes (LEDs) and lasers; however, the behavior of these materials under the intense electrical excitation required for electrically-pumped lasing remains unexplored. Here, we investigate methylammonium lead iodide-based perovskite LEDs under short pulsed drive at current densities up to 620 A cm−2. At low current density (J < 10 A cm−2), we find that the external quantum efficiency (EQE) depends strongly on the time-averaged history of the pulse train and show that this curiosity is associated with slow ion movement that changes the internal field distribution and trap density in the device. The impact of ions is less pronounced in the high current density regime (J > 10 A cm−2), where EQE roll-off is dominated by a combination of Joule heating and charge imbalance yet shows no evidence of Auger loss, suggesting that operation at kA cm−2 current densities relevant for a laser diode should be within reach.

Original languageEnglish (US)
Article number4893
JournalNature communications
Volume9
Issue number1
DOIs
StatePublished - Dec 1 2018

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

Fingerprint Dive into the research topics of 'Hybrid perovskite light emitting diodes under intense electrical excitation'. Together they form a unique fingerprint.

Cite this