How long do regions of different dynamics persist in supercooled o-terphenyl?

Chia-Ying Wang, M. D. Ediger

Research output: Contribution to journalArticle

114 Scopus citations

Abstract

In supercooled o-terphenyl (OTP), subsets of probe molecules in more mobile environments can be selectively photobleached. The time required for the remaining slower-than-average probes to be redistributed into an equilibrium set of environments has been measured. At Tg + 4 K (Tg = 243 K), this exchange time is 6 times greater than the average probe rotational correlation time. These results are compared to previous optical measurements at Tg + 1 K (Cicerone, M. T.; Ediger, M. D. J. Chem. Phys. 1995, 103, 5684), which showed that the exchange time is more than 100 times the rotational correlation time, and to multidimensional NMR experiments on deuterated OTP at Tg + 10 K (Bohmer, R.; et al. Europhys. Lett. 1996, 36, 55), which showed that the exchange time is nearly equal to the correlation time. These results in aggregate suggest that a new relaxation process in equilibrium supercooled liquids emerges only at temperatures very near Tg. A model for selective photobleaching is proposed. The model reproduces the experimental data reasonably well and indicates that the photobleaching efficiency of a given probe is only weakly correlated with its rotational correlation time.

Original languageEnglish (US)
Pages (from-to)4177-4184
Number of pages8
JournalJournal of Physical Chemistry B
Volume103
Issue number20
StatePublished - Dec 1 1999
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

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