Highly selective bis(imino)pyridine iron-catalyzed alkene hydroboration

Jennifer V. Obligacion; Paul J. Chirik

doi:10.1021/ol400990u

Highly selective bis(imino)pyridine iron-catalyzed alkene hydroboration

Jennifer V. Obligacion, Paul J. Chirik

Chemistry

Research output: Contribution to journal › Article › peer-review

176 Scopus citations

Abstract

Bis(imino)pyridine iron dinitrogen complexes have been shown to promote the anti-Markovnikov catalytic hydroboration of terminal, internal, and geminal alkenes with high activity and selectivity. The isolated iron dinitrogen compounds offer distinct advantages in substrate scope and overall performance over known precious metal catalysts and previously reported in situ generated iron species.

Original language	English (US)
Pages (from-to)	2680-2683
Number of pages	4
Journal	Organic letters
Volume	15
Issue number	11
DOIs	https://doi.org/10.1021/ol400990u
State	Published - Jun 7 2013

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol400990u

Cite this

@article{c0ae6b57210742c09583bbd35366ffb0,

title = "Highly selective bis(imino)pyridine iron-catalyzed alkene hydroboration",

abstract = "Bis(imino)pyridine iron dinitrogen complexes have been shown to promote the anti-Markovnikov catalytic hydroboration of terminal, internal, and geminal alkenes with high activity and selectivity. The isolated iron dinitrogen compounds offer distinct advantages in substrate scope and overall performance over known precious metal catalysts and previously reported in situ generated iron species.",

author = "Obligacion, {Jennifer V.} and Chirik, {Paul J.}",

year = "2013",

month = jun,

day = "7",

doi = "10.1021/ol400990u",

language = "English (US)",

volume = "15",

pages = "2680--2683",

journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Highly selective bis(imino)pyridine iron-catalyzed alkene hydroboration

AU - Obligacion, Jennifer V.

AU - Chirik, Paul J.

PY - 2013/6/7

Y1 - 2013/6/7

N2 - Bis(imino)pyridine iron dinitrogen complexes have been shown to promote the anti-Markovnikov catalytic hydroboration of terminal, internal, and geminal alkenes with high activity and selectivity. The isolated iron dinitrogen compounds offer distinct advantages in substrate scope and overall performance over known precious metal catalysts and previously reported in situ generated iron species.

AB - Bis(imino)pyridine iron dinitrogen complexes have been shown to promote the anti-Markovnikov catalytic hydroboration of terminal, internal, and geminal alkenes with high activity and selectivity. The isolated iron dinitrogen compounds offer distinct advantages in substrate scope and overall performance over known precious metal catalysts and previously reported in situ generated iron species.

UR - http://www.scopus.com/inward/record.url?scp=84879241186&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84879241186&partnerID=8YFLogxK

U2 - 10.1021/ol400990u

DO - 10.1021/ol400990u

M3 - Article

C2 - 23688021

AN - SCOPUS:84879241186

SN - 1523-7060

VL - 15

SP - 2680

EP - 2683

JO - Organic letters

JF - Organic letters

IS - 11

ER -

Highly selective bis(imino)pyridine iron-catalyzed alkene hydroboration

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this