High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

Crisita Carmen Hojilla Atienza; Aaron M. Tondreau; Keith J. Weller; Kenrick M. Lewis; Richard W. Cruse; Susan A. Nye; Julie L. Boyer; Johannes G.P. Delis; Paul J. Chirik

doi:10.1021/cs300584b

High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

Crisita Carmen Hojilla Atienza
, Aaron M. Tondreau
, Keith J. Weller
, Kenrick M. Lewis
, Richard W. Cruse
, Susan A. Nye
, Julie L. Boyer
, Johannes G.P. Delis
, Paul J. Chirik

Chemistry

Research output: Contribution to journal › Article › peer-review

116 Scopus citations

Abstract

Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4- trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.

Original language	English (US)
Pages (from-to)	2169-2172
Number of pages	4
Journal	ACS Catalysis
Volume	2
Issue number	10
DOIs	https://doi.org/10.1021/cs300584b
State	Published - Oct 5 2012

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

Catalysis
Hydrosilylation
Iron
Silane
Trivinylcyclohexene

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10.1021/cs300584b

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title = "High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane",

abstract = "Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4- trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.",

keywords = "Catalysis, Hydrosilylation, Iron, Silane, Trivinylcyclohexene",

author = "Atienza, \{Crisita Carmen Hojilla\} and Tondreau, \{Aaron M.\} and Weller, \{Keith J.\} and Lewis, \{Kenrick M.\} and Cruse, \{Richard W.\} and Nye, \{Susan A.\} and Boyer, \{Julie L.\} and Delis, \{Johannes G.P.\} and Chirik, \{Paul J.\}",

year = "2012",

month = oct,

day = "5",

doi = "10.1021/cs300584b",

language = "English (US)",

volume = "2",

pages = "2169--2172",

journal = "ACS Catalysis",

issn = "2155-5435",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

AU - Atienza, Crisita Carmen Hojilla

AU - Tondreau, Aaron M.

AU - Weller, Keith J.

AU - Lewis, Kenrick M.

AU - Cruse, Richard W.

AU - Nye, Susan A.

AU - Boyer, Julie L.

AU - Delis, Johannes G.P.

AU - Chirik, Paul J.

PY - 2012/10/5

Y1 - 2012/10/5

N2 - Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4- trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.

AB - Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4- trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.

KW - Catalysis

KW - Hydrosilylation

KW - Iron

KW - Silane

KW - Trivinylcyclohexene

UR - https://www.scopus.com/pages/publications/84867510141

UR - https://www.scopus.com/pages/publications/84867510141#tab=citedBy

U2 - 10.1021/cs300584b

DO - 10.1021/cs300584b

M3 - Article

AN - SCOPUS:84867510141

SN - 2155-5435

VL - 2

SP - 2169

EP - 2172

JO - ACS Catalysis

JF - ACS Catalysis

IS - 10

ER -

High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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