High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

Crisita Carmen Hojilla Atienza; Aaron M. Tondreau; Keith J. Weller; Kenrick M. Lewis; Richard W. Cruse; Susan A. Nye; Julie L. Boyer; Johannes G.P. Delis; Paul J. Chirik

doi:10.1021/cs300584b

High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

Crisita Carmen Hojilla Atienza, Aaron M. Tondreau, Keith J. Weller, Kenrick M. Lewis, Richard W. Cruse, Susan A. Nye, Julie L. Boyer, Johannes G.P. Delis, Paul J. Chirik

Chemistry

Research output: Contribution to journal › Article › peer-review

112 Scopus citations

Abstract

Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4- trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.

Original language	English (US)
Pages (from-to)	2169-2172
Number of pages	4
Journal	ACS Catalysis
Volume	2
Issue number	10
DOIs	https://doi.org/10.1021/cs300584b
State	Published - Oct 5 2012

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

Catalysis
Hydrosilylation
Iron
Silane
Trivinylcyclohexene

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10.1021/cs300584b

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title = "High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane",

abstract = "Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4- trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.",

keywords = "Catalysis, Hydrosilylation, Iron, Silane, Trivinylcyclohexene",

author = "Atienza, {Crisita Carmen Hojilla} and Tondreau, {Aaron M.} and Weller, {Keith J.} and Lewis, {Kenrick M.} and Cruse, {Richard W.} and Nye, {Susan A.} and Boyer, {Julie L.} and Delis, {Johannes G.P.} and Chirik, {Paul J.}",

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day = "5",

doi = "10.1021/cs300584b",

language = "English (US)",

volume = "2",

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journal = "ACS Catalysis",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

AU - Atienza, Crisita Carmen Hojilla

AU - Tondreau, Aaron M.

AU - Weller, Keith J.

AU - Lewis, Kenrick M.

AU - Cruse, Richard W.

AU - Nye, Susan A.

AU - Boyer, Julie L.

AU - Delis, Johannes G.P.

AU - Chirik, Paul J.

PY - 2012/10/5

Y1 - 2012/10/5

N2 - Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4- trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.

AB - Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4- trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.

KW - Catalysis

KW - Hydrosilylation

KW - Iron

KW - Silane

KW - Trivinylcyclohexene

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U2 - 10.1021/cs300584b

DO - 10.1021/cs300584b

M3 - Article

AN - SCOPUS:84867510141

SN - 2155-5435

VL - 2

SP - 2169

EP - 2172

JO - ACS Catalysis

JF - ACS Catalysis

IS - 10

ER -

High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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