High electrical conductivity in Ni3(2,3,6,7,10,11- hexaiminotriphenylene)2, a semiconducting metal-organic graphene analogue

Dennis Sheberla; Lei Sun; Martin A. Blood-Forsythe; Süleyman Er; Casey R. Wade; Carl K. Brozek; Alán Aspuru-Guzik; Mircea Dincǎ

doi:10.1021/ja502765n

High electrical conductivity in Ni₃(2,3,6,7,10,11- hexaiminotriphenylene)₂, a semiconducting metal-organic graphene analogue

Dennis Sheberla
, Lei Sun
, Martin A. Blood-Forsythe
, Süleyman Er
, Casey R. Wade
, Carl K. Brozek
, Alán Aspuru-Guzik
, Mircea Dincǎ

Research output: Contribution to journal › Article › peer-review

1068 Scopus citations

Abstract

Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni²⁺ in aqueous NH₃ solution under aerobic conditions produces Ni ₃(HITP)₂ (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal-organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm^-1, respectively, both records for MOFs and among the best for any coordination polymer.

Original language	English (US)
Pages (from-to)	8859-8862
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	25
DOIs	https://doi.org/10.1021/ja502765n
State	Published - Jun 25 2014
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja502765n

Cite this

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title = "High electrical conductivity in Ni3(2,3,6,7,10,11- hexaiminotriphenylene)2, a semiconducting metal-organic graphene analogue",

abstract = "Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni 3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal-organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm-1, respectively, both records for MOFs and among the best for any coordination polymer.",

author = "Dennis Sheberla and Lei Sun and Blood-Forsythe, \{Martin A.\} and S{\"u}leyman Er and Wade, \{Casey R.\} and Brozek, \{Carl K.\} and Al{\'a}n Aspuru-Guzik and Mircea Dincǎ",

year = "2014",

month = jun,

day = "25",

doi = "10.1021/ja502765n",

language = "English (US)",

volume = "136",

pages = "8859--8862",

journal = "Journal of the American Chemical Society",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - High electrical conductivity in Ni3(2,3,6,7,10,11- hexaiminotriphenylene)2, a semiconducting metal-organic graphene analogue

AU - Sheberla, Dennis

AU - Sun, Lei

AU - Blood-Forsythe, Martin A.

AU - Er, Süleyman

AU - Wade, Casey R.

AU - Brozek, Carl K.

AU - Aspuru-Guzik, Alán

AU - Dincǎ, Mircea

PY - 2014/6/25

Y1 - 2014/6/25

N2 - Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni 3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal-organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm-1, respectively, both records for MOFs and among the best for any coordination polymer.

AB - Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni 3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal-organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm-1, respectively, both records for MOFs and among the best for any coordination polymer.

UR - https://www.scopus.com/pages/publications/84902260187

UR - https://www.scopus.com/pages/publications/84902260187#tab=citedBy

U2 - 10.1021/ja502765n

DO - 10.1021/ja502765n

M3 - Article

C2 - 24750124

AN - SCOPUS:84902260187

SN - 0002-7863

VL - 136

SP - 8859

EP - 8862

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 25

ER -

High electrical conductivity in Ni₃(2,3,6,7,10,11- hexaiminotriphenylene)₂, a semiconducting metal-organic graphene analogue

Abstract

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