TY - JOUR
T1 - High electrical conductivity in Ni3(2,3,6,7,10,11- hexaiminotriphenylene)2, a semiconducting metal-organic graphene analogue
AU - Sheberla, Dennis
AU - Sun, Lei
AU - Blood-Forsythe, Martin A.
AU - Er, Süleyman
AU - Wade, Casey R.
AU - Brozek, Carl K.
AU - Aspuru-Guzik, Alán
AU - Dincǎ, Mircea
PY - 2014/6/25
Y1 - 2014/6/25
N2 - Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni 3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal-organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm-1, respectively, both records for MOFs and among the best for any coordination polymer.
AB - Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni 3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal-organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm-1, respectively, both records for MOFs and among the best for any coordination polymer.
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U2 - 10.1021/ja502765n
DO - 10.1021/ja502765n
M3 - Article
C2 - 24750124
AN - SCOPUS:84902260187
SN - 0002-7863
VL - 136
SP - 8859
EP - 8862
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 25
ER -