High charge mobility in a tetrathiafulvalene-based microporous metal-organic framework

Tarun C. Narayan; Tomoyo Miyakai; Shu Seki; Mircea Dincǎ

doi:10.1021/ja3059827

High charge mobility in a tetrathiafulvalene-based microporous metal-organic framework

Tarun C. Narayan, Tomoyo Miyakai, Shu Seki, Mircea Dincǎ

Research output: Contribution to journal › Article › peer-review

469 Scopus citations

Abstract

The tetratopic ligand tetrathiafulvalene-tetrabenzoate (H ₄TTFTB) is used to synthesize Zn ₂(TTFTB), a new metal-organic framework that contains columnar stacks of tetrathiafulvalene and benzoate-lined infinite one-dimensional channels. The new MOF remains porous upon desolvation and exhibits charge mobility commensurate with some of the best organic semiconductors, confirmed by flash-photolysis-time-resolved microwave conductivity measurements. Zn ₂(TTFTB) represents the first example of a permanently porous MOF with high charge mobility and may inspire further exploration of the electronic properties of these materials.

Original language	English (US)
Pages (from-to)	12932-12935
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	31
DOIs	https://doi.org/10.1021/ja3059827
State	Published - Aug 8 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja3059827

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abstract = "The tetratopic ligand tetrathiafulvalene-tetrabenzoate (H 4TTFTB) is used to synthesize Zn 2(TTFTB), a new metal-organic framework that contains columnar stacks of tetrathiafulvalene and benzoate-lined infinite one-dimensional channels. The new MOF remains porous upon desolvation and exhibits charge mobility commensurate with some of the best organic semiconductors, confirmed by flash-photolysis-time-resolved microwave conductivity measurements. Zn 2(TTFTB) represents the first example of a permanently porous MOF with high charge mobility and may inspire further exploration of the electronic properties of these materials.",

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AU - Narayan, Tarun C.

AU - Miyakai, Tomoyo

AU - Seki, Shu

AU - Dincǎ, Mircea

PY - 2012/8/8

Y1 - 2012/8/8

N2 - The tetratopic ligand tetrathiafulvalene-tetrabenzoate (H 4TTFTB) is used to synthesize Zn 2(TTFTB), a new metal-organic framework that contains columnar stacks of tetrathiafulvalene and benzoate-lined infinite one-dimensional channels. The new MOF remains porous upon desolvation and exhibits charge mobility commensurate with some of the best organic semiconductors, confirmed by flash-photolysis-time-resolved microwave conductivity measurements. Zn 2(TTFTB) represents the first example of a permanently porous MOF with high charge mobility and may inspire further exploration of the electronic properties of these materials.

AB - The tetratopic ligand tetrathiafulvalene-tetrabenzoate (H 4TTFTB) is used to synthesize Zn 2(TTFTB), a new metal-organic framework that contains columnar stacks of tetrathiafulvalene and benzoate-lined infinite one-dimensional channels. The new MOF remains porous upon desolvation and exhibits charge mobility commensurate with some of the best organic semiconductors, confirmed by flash-photolysis-time-resolved microwave conductivity measurements. Zn 2(TTFTB) represents the first example of a permanently porous MOF with high charge mobility and may inspire further exploration of the electronic properties of these materials.

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High charge mobility in a tetrathiafulvalene-based microporous metal-organic framework

Abstract

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