We introduce one-parameter groups of transformations that effect wide-ranging changes in the rate constants and input/output fluxes of homogeneous chemical reactions involving an arbitrary number of species in reactions of zero, first and second order. Each one-parameter group is required to convert every solution of such elementary rate equations into corresponding solutions of a one-parameter family of altered elementary rate equations. The generators of all allowed one-parameter groups are obtained for systems with N species using an algorithm which exactly determines their action on the rate constants, and either exactly determines or systematically approximates their action on the concentrations. Compounding the one-parameter groups yields all many-parameter groups of smooth time-independent transformations that interconvert elementary rate equations and their solutions.
|Original language||English (US)|
|Number of pages||17|
|Journal||Journal of Mathematical Chemistry|
|State||Published - Jul 1 1989|
All Science Journal Classification (ASJC) codes
- Applied Mathematics