Glasses from colloids

George Scherer, John C. Luong

Research output: Contribution to journalArticle

86 Scopus citations

Abstract

A process is described for preparation of glass from colloidal dispersions of particles produced by flame oxidation. Particles of SiO2 made from SiCl4 (BET diameter ∼ 60 nm) are dispersed in a hydrophobic solvent by an adsorbed layer of alcohol molecules. The adsorption sites are shown by photoacoustic spectroscopy to be isolated silanol (SiOH) groups on the surface of the particles. The alcohol presents a steric barrier to coagulation of the colloid, so that a suspension of 13 vol.% of SiO2 retains a viscosity below 50 cP for weeks. The silanol is acidic, so more basic alcohols adsorb more strongly; e.g. 1-propanol disperses silica, but methanol does not, nor does more acidic fluorinated propanol (C3F7OH). The colloid is readily gelled by exposure to a base, such as an alkyl amine or NH3, which deprotonates the silanol. The resulting charges cause gelling, in qualitative agreement with the theory of Féat and Levine. Evaporation of the solvent is readily achieved to obtain a hydrophobic gel containing ∼ 65-75% porosity. A cylindrical monolith ∼ 1.3 × 19 cm can be dried in 3 days, then sintered to clear glass at 1300-1400°C.

Original languageEnglish (US)
Pages (from-to)163-172
Number of pages10
JournalJournal of Non-Crystalline Solids
Volume63
Issue number1-2
DOIs
StatePublished - Jan 1 1984

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

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