Germaindacenodithiophene based low band gap polymers for organic solar cells

Zhuping Fei; Raja Shahid Ashraf; Zhenggang Huang; Jeremy Smith; R. Joseph Kline; Pasquale D’angelo; Thomas D. Anthopoulos; James R. Durrant; Iain McCulloch; Martin Heeney

doi:10.1039/c2cc17996b

Germaindacenodithiophene based low band gap polymers for organic solar cells

Zhuping Fei
, Raja Shahid Ashraf
, Zhenggang Huang
, Jeremy Smith
, R. Joseph Kline
, Pasquale D’angelo
, Thomas D. Anthopoulos
, James R. Durrant
, Iain McCulloch
, Martin Heeney

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

We report the first synthesis of a fused germaindacenodithiophene monomer and its polymerisation with 2,1,3-benzothiadiazole by Suzuki polycondensation. The resulting polymer, PGeTPTBT, is semicrystalline, despite the presence of four bulky 2-ethylhexyl groups. Blends with P₇₀CBM afford solar cells with efficiencies of 5.02%.

Original language	English (US)
Pages (from-to)	2955-2957
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	24
DOIs	https://doi.org/10.1039/c2cc17996b
State	Published - Feb 22 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc17996b

Cite this

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title = "Germaindacenodithiophene based low band gap polymers for organic solar cells",

abstract = "We report the first synthesis of a fused germaindacenodithiophene monomer and its polymerisation with 2,1,3-benzothiadiazole by Suzuki polycondensation. The resulting polymer, PGeTPTBT, is semicrystalline, despite the presence of four bulky 2-ethylhexyl groups. Blends with P70CBM afford solar cells with efficiencies of 5.02\%.",

author = "Zhuping Fei and Ashraf, \{Raja Shahid\} and Zhenggang Huang and Jeremy Smith and Kline, \{R. Joseph\} and Pasquale D{\textquoteright}angelo and Anthopoulos, \{Thomas D.\} and Durrant, \{James R.\} and Iain McCulloch and Martin Heeney",

year = "2012",

month = feb,

day = "22",

doi = "10.1039/c2cc17996b",

language = "English (US)",

volume = "48",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Germaindacenodithiophene based low band gap polymers for organic solar cells

AU - Fei, Zhuping

AU - Ashraf, Raja Shahid

AU - Huang, Zhenggang

AU - Smith, Jeremy

AU - Kline, R. Joseph

AU - D’angelo, Pasquale

AU - Anthopoulos, Thomas D.

AU - Durrant, James R.

AU - McCulloch, Iain

AU - Heeney, Martin

PY - 2012/2/22

Y1 - 2012/2/22

N2 - We report the first synthesis of a fused germaindacenodithiophene monomer and its polymerisation with 2,1,3-benzothiadiazole by Suzuki polycondensation. The resulting polymer, PGeTPTBT, is semicrystalline, despite the presence of four bulky 2-ethylhexyl groups. Blends with P70CBM afford solar cells with efficiencies of 5.02%.

AB - We report the first synthesis of a fused germaindacenodithiophene monomer and its polymerisation with 2,1,3-benzothiadiazole by Suzuki polycondensation. The resulting polymer, PGeTPTBT, is semicrystalline, despite the presence of four bulky 2-ethylhexyl groups. Blends with P70CBM afford solar cells with efficiencies of 5.02%.

UR - https://www.scopus.com/pages/publications/84863169449

UR - https://www.scopus.com/pages/publications/84863169449#tab=citedBy

U2 - 10.1039/c2cc17996b

DO - 10.1039/c2cc17996b

M3 - Article

C2 - 22318622

AN - SCOPUS:84863169449

SN - 1359-7345

VL - 48

SP - 2955

EP - 2957

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Germaindacenodithiophene based low band gap polymers for organic solar cells

Abstract

All Science Journal Classification (ASJC) codes

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