Further evidence for spontaneous solid-state polymerisation reactions in 2,5-dibromothiophene derivatives

  • Howard J. Spencer
  • , Rory Berridge
  • , David J. Crouch
  • , Shaun P. Wright
  • , Mark Giles
  • , Iain McCulloch
  • , Simon J. Coles
  • , Michael B. Hursthouse
  • , Peter J. Skabara

Research output: Contribution to journalArticlepeer-review

65 Scopus citations

Abstract

Three new, highly crystalline 2,5-dibromothiophene compounds polymerise on standing in the absence of solvent and catalyst; X-ray crystallography shows that the molecules are held in close proximity by several short intermolecular contacts, facilitating the coupling of monomers.

Original languageEnglish (US)
Pages (from-to)2075-2077
Number of pages3
JournalJournal of Materials Chemistry
Volume13
Issue number9
DOIs
StatePublished - Sep 1 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • Materials Chemistry

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